Co（III）催化2-烯基吡啶与2-乙烯基氮基吡啶的烯丙基化反应：得到1,4-二烯。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-10-15 DOI:10.1039/d5ob01343g

Hong Zeng, Zhong-Xia Wang

引用次数: 0

摘要

描述了一个Cp*(CO) co2催化的2-烯基吡啶与2-乙烯基氮基吡啶的C-H烯丙基化反应。这种方法提供了合成有用的1,4-二烯骨架的有效途径。该方法具有反应体系简单、含氮基团保留、原子经济、反应时间短、底物范围广、对官能团耐受性好等特点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Co(III)-catalyzed allylation reaction of 2-alkenylpyridines with 2-vinylaziridines: access to 1,4-dienes.

A Cp*(CO)CoI₂-catalyzed C-H allylation of 2-alkenylpyridines with 2-vinylaziridines is described. This method provides efficient access to synthetically useful 1,4-diene skeletons. The approach features a simple reaction system, nitrogen-containing group retainment, atom economy, short reaction times, wide substrate scope and good tolerance towards functional groups.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.