从下面加热的嗜热胶体悬浮液中长波长非平衡温度波动的猝灭。

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL
Stefano Castellini, Alberto Vailati
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引用次数: 0

摘要

我们从理论上研究了水中强亲热性二氧化硅纳米颗粒胶状悬浮液中非平衡温度和浓度波动的时空相关性,其分离比基本上小于-1。当系统从下面绝热加热时,对流被抑制,即使在瑞利-巴姆纳德阈值之上,因为纳米颗粒在底部边界积聚并产生稳定的密度梯度。在这些条件下,我们发现长波长的温度波动被稳定的浓度曲线所猝灭。同时,宏观温度梯度在很大程度上影响了浓度波动,减少了它们在小波矢量处的过稳定。悬浮液的强亲热性导致温度和浓度波动之间呈负相关,在小波矢量处产生功率谱的明显下降。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Quenching of long-wavelength non-equilibrium temperature fluctuations in a thermophilic colloidal suspension heated from below.

We theoretically investigate the spatial and temporal correlation properties of non-equilibrium temperature and concentration fluctuations in a colloidal suspension of strongly thermophilic silica nanoparticles in water, characterized by a separation ratio largely smaller than -1. When the system is adiabatically heated from below, convection is suppressed, even above the Rayleigh-Bénard threshold, because nanoparticles accumulate at the bottom boundary and create a stabilizing density gradient. Under these conditions, we show that long-wavelength temperature fluctuations are quenched by the stabilizing concentration profile. Meanwhile, the macroscopic temperature gradient largely influences concentration fluctuations, reducing their overstabilization at small wave vectors. The strong thermophilic behavior of the suspension leads to a negative cross correlation between temperature and concentration fluctuations, producing a distinctive dip in the power spectrum at small wave vectors.

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来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
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