{"title":"从下面加热的嗜热胶体悬浮液中长波长非平衡温度波动的猝灭。","authors":"Stefano Castellini, Alberto Vailati","doi":"10.1063/5.0293787","DOIUrl":null,"url":null,"abstract":"<p><p>We theoretically investigate the spatial and temporal correlation properties of non-equilibrium temperature and concentration fluctuations in a colloidal suspension of strongly thermophilic silica nanoparticles in water, characterized by a separation ratio largely smaller than -1. When the system is adiabatically heated from below, convection is suppressed, even above the Rayleigh-Bénard threshold, because nanoparticles accumulate at the bottom boundary and create a stabilizing density gradient. Under these conditions, we show that long-wavelength temperature fluctuations are quenched by the stabilizing concentration profile. Meanwhile, the macroscopic temperature gradient largely influences concentration fluctuations, reducing their overstabilization at small wave vectors. The strong thermophilic behavior of the suspension leads to a negative cross correlation between temperature and concentration fluctuations, producing a distinctive dip in the power spectrum at small wave vectors.</p>","PeriodicalId":15313,"journal":{"name":"Journal of Chemical Physics","volume":"163 14","pages":""},"PeriodicalIF":3.1000,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Quenching of long-wavelength non-equilibrium temperature fluctuations in a thermophilic colloidal suspension heated from below.\",\"authors\":\"Stefano Castellini, Alberto Vailati\",\"doi\":\"10.1063/5.0293787\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>We theoretically investigate the spatial and temporal correlation properties of non-equilibrium temperature and concentration fluctuations in a colloidal suspension of strongly thermophilic silica nanoparticles in water, characterized by a separation ratio largely smaller than -1. When the system is adiabatically heated from below, convection is suppressed, even above the Rayleigh-Bénard threshold, because nanoparticles accumulate at the bottom boundary and create a stabilizing density gradient. Under these conditions, we show that long-wavelength temperature fluctuations are quenched by the stabilizing concentration profile. Meanwhile, the macroscopic temperature gradient largely influences concentration fluctuations, reducing their overstabilization at small wave vectors. The strong thermophilic behavior of the suspension leads to a negative cross correlation between temperature and concentration fluctuations, producing a distinctive dip in the power spectrum at small wave vectors.</p>\",\"PeriodicalId\":15313,\"journal\":{\"name\":\"Journal of Chemical Physics\",\"volume\":\"163 14\",\"pages\":\"\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Physics\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1063/5.0293787\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1063/5.0293787","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Quenching of long-wavelength non-equilibrium temperature fluctuations in a thermophilic colloidal suspension heated from below.
We theoretically investigate the spatial and temporal correlation properties of non-equilibrium temperature and concentration fluctuations in a colloidal suspension of strongly thermophilic silica nanoparticles in water, characterized by a separation ratio largely smaller than -1. When the system is adiabatically heated from below, convection is suppressed, even above the Rayleigh-Bénard threshold, because nanoparticles accumulate at the bottom boundary and create a stabilizing density gradient. Under these conditions, we show that long-wavelength temperature fluctuations are quenched by the stabilizing concentration profile. Meanwhile, the macroscopic temperature gradient largely influences concentration fluctuations, reducing their overstabilization at small wave vectors. The strong thermophilic behavior of the suspension leads to a negative cross correlation between temperature and concentration fluctuations, producing a distinctive dip in the power spectrum at small wave vectors.
期刊介绍:
The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance.
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