Rafael S Xavier, Thiago S Dias, Débora F de Andrade, Daniella L Vale, Cristiane G de Souza, Luiz Antonio d'Avila
{"title":"基于计算机视觉和比色法测定BX柴油中生物柴油含量的便携式设备的研制。","authors":"Rafael S Xavier, Thiago S Dias, Débora F de Andrade, Daniella L Vale, Cristiane G de Souza, Luiz Antonio d'Avila","doi":"10.1039/d5ay01251a","DOIUrl":null,"url":null,"abstract":"<p><p>This study presents a low-cost, 3D-printed portable device that integrates computer vision and an artificial neural network (ANN) to quantify biodiesel content (1-30% v/v) in fossil diesel blends using a solvatochromic assay with Reichardt's dye. A total of 105 samples (35 biodiesel blend levels in triplicate) were analyzed with both the proposed method and the official Brazilian standard ABNT NBR 15568/2008 (FT-IR). While the standard method requires laboratory infrastructure and specialized equipment, the proposed system provides comparable accuracy directly at the point of fuel distribution. It achieved a mean absolute error (MAE) of 1.5% (<i>R</i><sup>2</sup> = 0.969) for training data and 0.5% (<i>R</i><sup>2</sup> = 0.995) for independent test data. Robust cross-validation confirmed model stability and absence of overfitting, and a paired Student's <i>t</i>-test showed no statistically significant difference between the two methods (<i>p</i> > 0.05), confirming statistical equivalence. Beyond analytical performance, the device offers practical advantages: controlled lighting and webcam-based image acquisition coupled with ANN processing enable rapid, on-site biodiesel determination without specialized training. This contrasts with the official method, which is restricted to laboratory settings. By combining portability, low operational complexity, and real-time analysis capability, this system represents a significant advancement for fuel quality monitoring, allowing reliable control of BX diesel blends directly at fueling stations and other non-laboratory environments. BX diesel, dye solution, and ethanol.</p>","PeriodicalId":64,"journal":{"name":"Analytical Methods","volume":" ","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of portable equipment based on computer vision and colorimetric assays to measure the biodiesel content in BX diesel.\",\"authors\":\"Rafael S Xavier, Thiago S Dias, Débora F de Andrade, Daniella L Vale, Cristiane G de Souza, Luiz Antonio d'Avila\",\"doi\":\"10.1039/d5ay01251a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>This study presents a low-cost, 3D-printed portable device that integrates computer vision and an artificial neural network (ANN) to quantify biodiesel content (1-30% v/v) in fossil diesel blends using a solvatochromic assay with Reichardt's dye. A total of 105 samples (35 biodiesel blend levels in triplicate) were analyzed with both the proposed method and the official Brazilian standard ABNT NBR 15568/2008 (FT-IR). While the standard method requires laboratory infrastructure and specialized equipment, the proposed system provides comparable accuracy directly at the point of fuel distribution. It achieved a mean absolute error (MAE) of 1.5% (<i>R</i><sup>2</sup> = 0.969) for training data and 0.5% (<i>R</i><sup>2</sup> = 0.995) for independent test data. Robust cross-validation confirmed model stability and absence of overfitting, and a paired Student's <i>t</i>-test showed no statistically significant difference between the two methods (<i>p</i> > 0.05), confirming statistical equivalence. Beyond analytical performance, the device offers practical advantages: controlled lighting and webcam-based image acquisition coupled with ANN processing enable rapid, on-site biodiesel determination without specialized training. This contrasts with the official method, which is restricted to laboratory settings. By combining portability, low operational complexity, and real-time analysis capability, this system represents a significant advancement for fuel quality monitoring, allowing reliable control of BX diesel blends directly at fueling stations and other non-laboratory environments. BX diesel, dye solution, and ethanol.</p>\",\"PeriodicalId\":64,\"journal\":{\"name\":\"Analytical Methods\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-10-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Methods\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5ay01251a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Methods","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5ay01251a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Development of portable equipment based on computer vision and colorimetric assays to measure the biodiesel content in BX diesel.
This study presents a low-cost, 3D-printed portable device that integrates computer vision and an artificial neural network (ANN) to quantify biodiesel content (1-30% v/v) in fossil diesel blends using a solvatochromic assay with Reichardt's dye. A total of 105 samples (35 biodiesel blend levels in triplicate) were analyzed with both the proposed method and the official Brazilian standard ABNT NBR 15568/2008 (FT-IR). While the standard method requires laboratory infrastructure and specialized equipment, the proposed system provides comparable accuracy directly at the point of fuel distribution. It achieved a mean absolute error (MAE) of 1.5% (R2 = 0.969) for training data and 0.5% (R2 = 0.995) for independent test data. Robust cross-validation confirmed model stability and absence of overfitting, and a paired Student's t-test showed no statistically significant difference between the two methods (p > 0.05), confirming statistical equivalence. Beyond analytical performance, the device offers practical advantages: controlled lighting and webcam-based image acquisition coupled with ANN processing enable rapid, on-site biodiesel determination without specialized training. This contrasts with the official method, which is restricted to laboratory settings. By combining portability, low operational complexity, and real-time analysis capability, this system represents a significant advancement for fuel quality monitoring, allowing reliable control of BX diesel blends directly at fueling stations and other non-laboratory environments. BX diesel, dye solution, and ethanol.