基于计算机视觉和比色法测定BX柴油中生物柴油含量的便携式设备的研制。

IF 2.6 3区 化学 Q2 CHEMISTRY, ANALYTICAL
Rafael S Xavier, Thiago S Dias, Débora F de Andrade, Daniella L Vale, Cristiane G de Souza, Luiz Antonio d'Avila
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引用次数: 0

摘要

本研究提出了一种低成本的3d打印便携式设备,该设备集成了计算机视觉和人工神经网络(ANN),使用Reichardt's染料的溶剂化变色试验来量化化石柴油混合物中生物柴油的含量(1-30% v/v)。采用所提出的方法和巴西官方标准ABNT NBR 15568/2008 (FT-IR)对105个样品(35种生物柴油混合水平,一式三份)进行了分析。虽然标准方法需要实验室基础设施和专用设备,但提议的系统在燃料分配点直接提供相当的准确性。训练数据的平均绝对误差(MAE)为1.5% (R2 = 0.969),独立测试数据的平均绝对误差(MAE)为0.5% (R2 = 0.995)。鲁棒交叉验证证实了模型的稳定性和不存在过拟合,配对Student's t检验显示两种方法之间无统计学显著差异(p > 0.05),证实了统计等效。除了分析性能外,该设备还具有实用优势:控制照明和基于网络摄像头的图像采集,加上人工神经网络处理,无需专门培训即可快速现场测定生物柴油。这与仅限于实验室环境的官方方法形成对比。该系统结合了便携性、低操作复杂性和实时分析能力,代表了燃料质量监测的重大进步,可以直接在加油站和其他非实验室环境中可靠地控制BX柴油混合物。BX柴油,染料溶液和乙醇。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development of portable equipment based on computer vision and colorimetric assays to measure the biodiesel content in BX diesel.

This study presents a low-cost, 3D-printed portable device that integrates computer vision and an artificial neural network (ANN) to quantify biodiesel content (1-30% v/v) in fossil diesel blends using a solvatochromic assay with Reichardt's dye. A total of 105 samples (35 biodiesel blend levels in triplicate) were analyzed with both the proposed method and the official Brazilian standard ABNT NBR 15568/2008 (FT-IR). While the standard method requires laboratory infrastructure and specialized equipment, the proposed system provides comparable accuracy directly at the point of fuel distribution. It achieved a mean absolute error (MAE) of 1.5% (R2 = 0.969) for training data and 0.5% (R2 = 0.995) for independent test data. Robust cross-validation confirmed model stability and absence of overfitting, and a paired Student's t-test showed no statistically significant difference between the two methods (p > 0.05), confirming statistical equivalence. Beyond analytical performance, the device offers practical advantages: controlled lighting and webcam-based image acquisition coupled with ANN processing enable rapid, on-site biodiesel determination without specialized training. This contrasts with the official method, which is restricted to laboratory settings. By combining portability, low operational complexity, and real-time analysis capability, this system represents a significant advancement for fuel quality monitoring, allowing reliable control of BX diesel blends directly at fueling stations and other non-laboratory environments. BX diesel, dye solution, and ethanol.

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来源期刊
Analytical Methods
Analytical Methods CHEMISTRY, ANALYTICAL-FOOD SCIENCE & TECHNOLOGY
CiteScore
5.10
自引率
3.20%
发文量
569
审稿时长
1.8 months
期刊介绍: Early applied demonstrations of new analytical methods with clear societal impact
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