Diyao Zhang , Sheng Qu , Zijun Peng , Zhenli Liu , Jingkun Yu , Lei Yuan
{"title":"高效耐钢水侵蚀和高温氧化WC-Cr3C2-Ni涂层的制备与研究","authors":"Diyao Zhang , Sheng Qu , Zijun Peng , Zhenli Liu , Jingkun Yu , Lei Yuan","doi":"10.1016/j.jiec.2025.05.011","DOIUrl":null,"url":null,"abstract":"<div><div>This study focused on the threat of molten steel erosion in the failure of the WC–Cr<sub>3</sub>C<sub>2</sub><span><span>–Ni coating on the surface of the crystallization roller. An innovative experimental method for dipping low-melting-point metal surface coatings against high-temperature </span>liquid metal erosion was proposed, filling the gap in experimental technology in this field. The WC–Cr</span><sub>3</sub>C<sub>2</sub><span>–Ni coating demonstrated excellent resistance to scouring erosion and high-temperature oxidation when exposed to long-term molten steel erosion during service. After 500 tons of steel throughput equivalent, the roller body performance did not decrease, and the hardness of the WC–Cr</span><sub>3</sub>C<sub>2</sub>–Ni coating was only reduced from 1298.75 Hv<sub>0.5</sub> to 1265.21 Hv<sub>0.5</sub> (by only 0.8 %). During the service process, the molten steel could not permeate into the WC–Cr<sub>3</sub>C<sub>2</sub><span><span>–Ni coating, and only micron-sized spherical steel slag particles (particle size 1–3 μm) were left on the </span>coating surface. This study made it clear that the erosion of molten steel played a weak influencing factor in the failure of the production line. The experimental results provide a theoretical basis for the life evaluation of crystallization rollers and the prediction of production line maintenance time.</span></div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"152 ","pages":"Pages 423-431"},"PeriodicalIF":5.9000,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and research of WC–Cr3C2–Ni coating with efficient resistance to molten steel erosion and high-temperature oxidation\",\"authors\":\"Diyao Zhang , Sheng Qu , Zijun Peng , Zhenli Liu , Jingkun Yu , Lei Yuan\",\"doi\":\"10.1016/j.jiec.2025.05.011\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study focused on the threat of molten steel erosion in the failure of the WC–Cr<sub>3</sub>C<sub>2</sub><span><span>–Ni coating on the surface of the crystallization roller. An innovative experimental method for dipping low-melting-point metal surface coatings against high-temperature </span>liquid metal erosion was proposed, filling the gap in experimental technology in this field. The WC–Cr</span><sub>3</sub>C<sub>2</sub><span>–Ni coating demonstrated excellent resistance to scouring erosion and high-temperature oxidation when exposed to long-term molten steel erosion during service. After 500 tons of steel throughput equivalent, the roller body performance did not decrease, and the hardness of the WC–Cr</span><sub>3</sub>C<sub>2</sub>–Ni coating was only reduced from 1298.75 Hv<sub>0.5</sub> to 1265.21 Hv<sub>0.5</sub> (by only 0.8 %). During the service process, the molten steel could not permeate into the WC–Cr<sub>3</sub>C<sub>2</sub><span><span>–Ni coating, and only micron-sized spherical steel slag particles (particle size 1–3 μm) were left on the </span>coating surface. This study made it clear that the erosion of molten steel played a weak influencing factor in the failure of the production line. The experimental results provide a theoretical basis for the life evaluation of crystallization rollers and the prediction of production line maintenance time.</span></div></div>\",\"PeriodicalId\":363,\"journal\":{\"name\":\"Journal of Industrial and Engineering Chemistry\",\"volume\":\"152 \",\"pages\":\"Pages 423-431\"},\"PeriodicalIF\":5.9000,\"publicationDate\":\"2025-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Industrial and Engineering Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1226086X25003223\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Industrial and Engineering Chemistry","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1226086X25003223","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation and research of WC–Cr3C2–Ni coating with efficient resistance to molten steel erosion and high-temperature oxidation
This study focused on the threat of molten steel erosion in the failure of the WC–Cr3C2–Ni coating on the surface of the crystallization roller. An innovative experimental method for dipping low-melting-point metal surface coatings against high-temperature liquid metal erosion was proposed, filling the gap in experimental technology in this field. The WC–Cr3C2–Ni coating demonstrated excellent resistance to scouring erosion and high-temperature oxidation when exposed to long-term molten steel erosion during service. After 500 tons of steel throughput equivalent, the roller body performance did not decrease, and the hardness of the WC–Cr3C2–Ni coating was only reduced from 1298.75 Hv0.5 to 1265.21 Hv0.5 (by only 0.8 %). During the service process, the molten steel could not permeate into the WC–Cr3C2–Ni coating, and only micron-sized spherical steel slag particles (particle size 1–3 μm) were left on the coating surface. This study made it clear that the erosion of molten steel played a weak influencing factor in the failure of the production line. The experimental results provide a theoretical basis for the life evaluation of crystallization rollers and the prediction of production line maintenance time.
期刊介绍:
Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.