通过环状DNA分子结的自旋过滤:外场与手性。

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL
Sheng'ao Zhang, Feng Jiang, Yonghong Yan, Yanyan Zhu
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引用次数: 0

摘要

为了深入理解螺旋分子链中所谓的手性诱导自旋选择性效应,我们建立了一个二次量子化形式的自旋轨道相互作用模型来描述圆螺旋结构。然后,我们利用标准的非平衡格林函数理论研究了DNA环状分子结的自旋过滤,发现了电导中一般的自旋依赖边带共振结构。利用环状DNA分子的自然结构,进一步证明了非磁性体系独特的自旋过滤Aharonov-Bohm效应,以及自旋极化、外场和手性之间的关系。在自旋滤波Aharonov-Bohm效应的调制中,临界横向电场的存在是非常有趣和鼓舞人心的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Spin filtering through circular DNA molecular junctions: External field vs chirality.

To gain an in-depth understanding of the so-called Chiral-Induced Spin Selectivity effect in helical molecular chains, we developed a spin-orbit interaction model in second-quantized form to describe the circular helical structure. We then employed the standard non-equilibrium Green's function theory to study spin filtering through circular DNA molecular junctions and found the general spin-dependent sideband resonance structure in conductance. By utilizing the natural structure of circular DNA molecules, we further demonstrated the unique spin-filtering Aharonov-Bohm effect of non-magnetic systems and the relationship between spin polarization, external fields, and chirality. The existence of a critical transverse electric field in the modulation of the spin-filtering Aharonov-Bohm effect is especially very interesting and inspiring.

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来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
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