Olli J. Pakkanen, J. Mikko Rautiainen, Raija Oilunkaniemi, Tristram Chivers, Heikki M. Tuononen, Risto S. Laitinen
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引用次数: 0
摘要
前盖介绍了通过sell2和tBuNH2的环缩合分离和鉴定的环有机亚胺硒和无环亚胺硒氯化物。硒这个名字来源于希腊语中月亮的名字selene。在他们的研究文章(DOI: 10.1002/ejic。202500292), H. M. Tuononen, R. S. Laitinen及其同事提出了详细的DFT计算,描述了复杂的反应路线,包括关键中间产物的形成,链延伸和环闭合的基本步骤,以类似的方式提出了环磷酰胺和-磷酰胺的形成。有些步骤还涉及氧化还原过程。
Front Cover: Formation of Cyclic Selenium Imides via Acyclic Selenium Imide Chlorides in Cyclocondensation of Selenium Dichloride with tert-Butylamine (Eur. J. Inorg. Chem. 28/2025)
The Front Cover describes the cyclic organic selenium imides and acyclic imidoselenium chlorides that have been isolated and identified upon cyclocondensation of SeCl2 and tBuNH2. The name selenium is derived from selene, the Greek name for the Moon. In their Research Article (DOI: 10.1002/ejic.202500292), H. M. Tuononen, R. S. Laitinen and co-workers present detailed DFT calculations that describe the complicated reaction route in terms of elementary steps involving key intermediate formation, chain extension, and ring closure, in a similar manner to what has been proposed for the formation of cyclophosphazanes and -phosphazenes. Some steps also involve redox processes.
期刊介绍:
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.