Xu-Dong Ma , Dan Zhang , Bai-Xin Dong , Hong-Yu Yang , Shi-Li Shu , Liang-Yu Chen , Fan Zhang , Jie Kang , Jia Meng , Cheng-Gang Wang , Kuang Cao , Jian Qiao , Feng Qiu , Qi-Chuan Jiang
{"title":"通过纳米陶瓷颗粒诱导的晶界稳定和析出控制提高AlCu合金的高温性能","authors":"Xu-Dong Ma , Dan Zhang , Bai-Xin Dong , Hong-Yu Yang , Shi-Li Shu , Liang-Yu Chen , Fan Zhang , Jie Kang , Jia Meng , Cheng-Gang Wang , Kuang Cao , Jian Qiao , Feng Qiu , Qi-Chuan Jiang","doi":"10.1016/j.matchar.2025.115628","DOIUrl":null,"url":null,"abstract":"<div><div>Al<img>Cu alloys are widely employed in the automotive and aerospace industries owing to their exceptional mechanical properties. However, their performance degradation at elevated temperatures restricts broader applications. Departing from conventional alloying approaches, this study introduces a novel strategy to enhance the high-temperature mechanical properties of Al<img>Cu alloys through grain boundary stabilization and precipitation manipulation via the incorporation of trace meticulously designed TiC–TiB₂ nanoceramic particles. These particles inhibit element segregation and facilitate the transformation of intergranular second phases into a finer, reticular structure, thereby stabilizing the grain boundaries. Additionally, the nanoparticles increase dislocation density, serving as preferential nucleation sites for precipitation. The larger lattice distortion around the precipitates also triggered the formation of stacking faults. Consequently, a more refined and uniform distribution of nano-precipitates enhances interactions with dislocations, imparting greater deformation resistance., The ultimate strength (310 MPa) and fracture strain (10.2 %) of 0.15 wt% particle reinforced Al<img>Cu alloy achieves a synergistic improvement in both high-temperature strength and toughness, which are improved by 28 % and 64 % at 473 K compared with the matrix alloy. This work offers valuable insights for developing high-performance, heat-resistant Al<img>Cu alloys, paving the way for advanced industrial applications.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"229 ","pages":"Article 115628"},"PeriodicalIF":5.5000,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhancing high-temperature performance of AlCu alloys via nanoceramic particle-induced grain boundary stabilization and precipitate manipulation\",\"authors\":\"Xu-Dong Ma , Dan Zhang , Bai-Xin Dong , Hong-Yu Yang , Shi-Li Shu , Liang-Yu Chen , Fan Zhang , Jie Kang , Jia Meng , Cheng-Gang Wang , Kuang Cao , Jian Qiao , Feng Qiu , Qi-Chuan Jiang\",\"doi\":\"10.1016/j.matchar.2025.115628\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Al<img>Cu alloys are widely employed in the automotive and aerospace industries owing to their exceptional mechanical properties. However, their performance degradation at elevated temperatures restricts broader applications. Departing from conventional alloying approaches, this study introduces a novel strategy to enhance the high-temperature mechanical properties of Al<img>Cu alloys through grain boundary stabilization and precipitation manipulation via the incorporation of trace meticulously designed TiC–TiB₂ nanoceramic particles. These particles inhibit element segregation and facilitate the transformation of intergranular second phases into a finer, reticular structure, thereby stabilizing the grain boundaries. Additionally, the nanoparticles increase dislocation density, serving as preferential nucleation sites for precipitation. The larger lattice distortion around the precipitates also triggered the formation of stacking faults. Consequently, a more refined and uniform distribution of nano-precipitates enhances interactions with dislocations, imparting greater deformation resistance., The ultimate strength (310 MPa) and fracture strain (10.2 %) of 0.15 wt% particle reinforced Al<img>Cu alloy achieves a synergistic improvement in both high-temperature strength and toughness, which are improved by 28 % and 64 % at 473 K compared with the matrix alloy. This work offers valuable insights for developing high-performance, heat-resistant Al<img>Cu alloys, paving the way for advanced industrial applications.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"229 \",\"pages\":\"Article 115628\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2025-10-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325009179\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325009179","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Enhancing high-temperature performance of AlCu alloys via nanoceramic particle-induced grain boundary stabilization and precipitate manipulation
AlCu alloys are widely employed in the automotive and aerospace industries owing to their exceptional mechanical properties. However, their performance degradation at elevated temperatures restricts broader applications. Departing from conventional alloying approaches, this study introduces a novel strategy to enhance the high-temperature mechanical properties of AlCu alloys through grain boundary stabilization and precipitation manipulation via the incorporation of trace meticulously designed TiC–TiB₂ nanoceramic particles. These particles inhibit element segregation and facilitate the transformation of intergranular second phases into a finer, reticular structure, thereby stabilizing the grain boundaries. Additionally, the nanoparticles increase dislocation density, serving as preferential nucleation sites for precipitation. The larger lattice distortion around the precipitates also triggered the formation of stacking faults. Consequently, a more refined and uniform distribution of nano-precipitates enhances interactions with dislocations, imparting greater deformation resistance., The ultimate strength (310 MPa) and fracture strain (10.2 %) of 0.15 wt% particle reinforced AlCu alloy achieves a synergistic improvement in both high-temperature strength and toughness, which are improved by 28 % and 64 % at 473 K compared with the matrix alloy. This work offers valuable insights for developing high-performance, heat-resistant AlCu alloys, paving the way for advanced industrial applications.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.