{"title":"欧洲大规模氢供应链的环境和经济评估:LOHC与其他氢技术","authors":"I. Rey, V.L. Barrio, I. Agirre","doi":"10.1016/j.apenergy.2025.126862","DOIUrl":null,"url":null,"abstract":"<div><div>The transition to decarbonized energy systems positions hydrogen as a critical vector for achieving climate neutrality, yet its large-scale transportation and storage remain key challenges. This study presents a comprehensive life cycle assessment (LCA) and economic analysis of large-scale H<sub>2</sub> supply chains, evaluating the liquid organic hydrogen carrier (LOHC) system based on benzyltoluene/perhydro-benzyltoluene (H0-BT/H12-BT) against conventional technologies: compressed gaseous hydrogen (CGH<sub>2</sub>), liquid hydrogen (LH<sub>2</sub>) and liquid ammonia (LNH<sub>3</sub>). The analysis includes multiple H<sub>2</sub> transportation scenarios across Europe, considering the steps: conditioning, sea transportation, post-processing and land distribution by truck or pipeline. Environmentally, LOHC currently faces higher environmental impacts than CGH<sub>2</sub>, driven by energy-intensive dehydrogenation process. Truck-based distribution further amplifies impacts, particularly over long distances, while pipeline-based distribution significantly reduces the environmental burdens where infrastructure exists. Sensitivity analysis reveals that using H<sub>2</sub> for dehydrogenation heat lowers process-level impacts but increases overall supply chain impacts, questioning its net environmental benefit. Economically, LOHC remains competitive despite high dehydrogenation costs, benefiting from low sea transportation expenses, compatibility with existing fossil fuel infrastructure and potential for future CAPEX and OPEX improvements. While CGH<sub>2</sub> outperforms LH<sub>2</sub> and LNH<sub>3</sub>, avoiding energy-intensive liquefaction and cracking, its storage requirements add considerable costs. For land distribution, LOHC trucks are optimal at lower capacities, whereas repurposed natural gas pipelines favour CGH<sub>2</sub> at higher scale, reducing costs by up to 84 %. Despite current trade-offs, the scalability, flexibility and synergies with existing infrastructure position LOHC as a promising solution for long-distance H<sub>2</sub> transport, contingent on technological maturation to mitigate dehydrogenation impacts.</div></div>","PeriodicalId":246,"journal":{"name":"Applied Energy","volume":"401 ","pages":"Article 126862"},"PeriodicalIF":11.0000,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Environmental and economic assessment of large-scale hydrogen supply chains across Europe: LOHC vs other hydrogen technologies\",\"authors\":\"I. Rey, V.L. Barrio, I. Agirre\",\"doi\":\"10.1016/j.apenergy.2025.126862\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The transition to decarbonized energy systems positions hydrogen as a critical vector for achieving climate neutrality, yet its large-scale transportation and storage remain key challenges. This study presents a comprehensive life cycle assessment (LCA) and economic analysis of large-scale H<sub>2</sub> supply chains, evaluating the liquid organic hydrogen carrier (LOHC) system based on benzyltoluene/perhydro-benzyltoluene (H0-BT/H12-BT) against conventional technologies: compressed gaseous hydrogen (CGH<sub>2</sub>), liquid hydrogen (LH<sub>2</sub>) and liquid ammonia (LNH<sub>3</sub>). The analysis includes multiple H<sub>2</sub> transportation scenarios across Europe, considering the steps: conditioning, sea transportation, post-processing and land distribution by truck or pipeline. Environmentally, LOHC currently faces higher environmental impacts than CGH<sub>2</sub>, driven by energy-intensive dehydrogenation process. Truck-based distribution further amplifies impacts, particularly over long distances, while pipeline-based distribution significantly reduces the environmental burdens where infrastructure exists. Sensitivity analysis reveals that using H<sub>2</sub> for dehydrogenation heat lowers process-level impacts but increases overall supply chain impacts, questioning its net environmental benefit. Economically, LOHC remains competitive despite high dehydrogenation costs, benefiting from low sea transportation expenses, compatibility with existing fossil fuel infrastructure and potential for future CAPEX and OPEX improvements. While CGH<sub>2</sub> outperforms LH<sub>2</sub> and LNH<sub>3</sub>, avoiding energy-intensive liquefaction and cracking, its storage requirements add considerable costs. For land distribution, LOHC trucks are optimal at lower capacities, whereas repurposed natural gas pipelines favour CGH<sub>2</sub> at higher scale, reducing costs by up to 84 %. Despite current trade-offs, the scalability, flexibility and synergies with existing infrastructure position LOHC as a promising solution for long-distance H<sub>2</sub> transport, contingent on technological maturation to mitigate dehydrogenation impacts.</div></div>\",\"PeriodicalId\":246,\"journal\":{\"name\":\"Applied Energy\",\"volume\":\"401 \",\"pages\":\"Article 126862\"},\"PeriodicalIF\":11.0000,\"publicationDate\":\"2025-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Energy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0306261925015922\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0306261925015922","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Environmental and economic assessment of large-scale hydrogen supply chains across Europe: LOHC vs other hydrogen technologies
The transition to decarbonized energy systems positions hydrogen as a critical vector for achieving climate neutrality, yet its large-scale transportation and storage remain key challenges. This study presents a comprehensive life cycle assessment (LCA) and economic analysis of large-scale H2 supply chains, evaluating the liquid organic hydrogen carrier (LOHC) system based on benzyltoluene/perhydro-benzyltoluene (H0-BT/H12-BT) against conventional technologies: compressed gaseous hydrogen (CGH2), liquid hydrogen (LH2) and liquid ammonia (LNH3). The analysis includes multiple H2 transportation scenarios across Europe, considering the steps: conditioning, sea transportation, post-processing and land distribution by truck or pipeline. Environmentally, LOHC currently faces higher environmental impacts than CGH2, driven by energy-intensive dehydrogenation process. Truck-based distribution further amplifies impacts, particularly over long distances, while pipeline-based distribution significantly reduces the environmental burdens where infrastructure exists. Sensitivity analysis reveals that using H2 for dehydrogenation heat lowers process-level impacts but increases overall supply chain impacts, questioning its net environmental benefit. Economically, LOHC remains competitive despite high dehydrogenation costs, benefiting from low sea transportation expenses, compatibility with existing fossil fuel infrastructure and potential for future CAPEX and OPEX improvements. While CGH2 outperforms LH2 and LNH3, avoiding energy-intensive liquefaction and cracking, its storage requirements add considerable costs. For land distribution, LOHC trucks are optimal at lower capacities, whereas repurposed natural gas pipelines favour CGH2 at higher scale, reducing costs by up to 84 %. Despite current trade-offs, the scalability, flexibility and synergies with existing infrastructure position LOHC as a promising solution for long-distance H2 transport, contingent on technological maturation to mitigate dehydrogenation impacts.
期刊介绍:
Applied Energy serves as a platform for sharing innovations, research, development, and demonstrations in energy conversion, conservation, and sustainable energy systems. The journal covers topics such as optimal energy resource use, environmental pollutant mitigation, and energy process analysis. It welcomes original papers, review articles, technical notes, and letters to the editor. Authors are encouraged to submit manuscripts that bridge the gap between research, development, and implementation. The journal addresses a wide spectrum of topics, including fossil and renewable energy technologies, energy economics, and environmental impacts. Applied Energy also explores modeling and forecasting, conservation strategies, and the social and economic implications of energy policies, including climate change mitigation. It is complemented by the open-access journal Advances in Applied Energy.