用于所有固态超级电容器应用的mxene增强的铈-氧化镧基纳米复合材料

IF 5.1 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS
P.E. Lokhande , Vishal Kadam , Chaitali Jagtap , Udayabhaskar Rednam , Bandar Ali Al-Asbahi , Aziz A. Aziz
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引用次数: 0

摘要

本研究讨论了微波辅助法制备的ceo2 - la2o3 - mxene基纳米复合材料在超级电容器中的应用。晶体学和形态学分析证实了MXene在氧化物基体中的成功分布,观察到在层状MXene结构上生长出薄的纳米氧化物片。表面分析显示,由于形貌的改变,表面积和孔隙度增加。电化学测量表明,在电流密度为2 a g−1时,比电容显著提高至1254 F g−1,优于裸氧化材料和复合氧化材料。此外,使用所制备的电极和活性炭作为电极材料制成的非对称固态器件的能量密度为31.33 Wh kg - 1,功率密度为3000 W kg - 1,在25000次循环后电容保持率为77%。该装置成功地为LED供电,说明了它的实用性。这些结果表明,导电MXene在CeO₂-La₂O₃中的掺入提高了电化学性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

MXene-boosted cerium‑lanthanum oxide-based nanocomposite for all solid state supercapacitor applications

MXene-boosted cerium‑lanthanum oxide-based nanocomposite for all solid state supercapacitor applications
This study discuss about CeO2-La2O3-MXene-based nanocomposite that was synthesized using a microwave-assisted method for supercapacitor applications. Crystallographic and morphological analyses confirmed the successful distribution of MXene in the oxide matrix, where thin nanosheets of oxides were observed to be grown on the layered MXene structure. Surface analysis revealed an increase in surface area and porosity due to the altered morphology. Electrochemical measurements shown a significantly enhanced specific capacitance of 1254 F g−1 at a current density of 2 A g−1, outperforming both the bare and combined oxide materials. Furthermore, an asymmetric solid-state device that fabricated by using the prepared electrode and activated carbon as electrode materials achieved an energy density of 31.33 Wh kg−1 and a power density of 3000 W kg−1, along with 77 % capacitance retention after 25,000 cycles. The device successfully powered an LED, illustrating its practical applicability. These results highlight that the incorporation of conductive MXene in CeO₂–La₂O₃ enhanced the electrochemical performance.
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来源期刊
Diamond and Related Materials
Diamond and Related Materials 工程技术-材料科学:综合
CiteScore
6.00
自引率
14.60%
发文量
702
审稿时长
2.1 months
期刊介绍: DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices. The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.
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