{"title":"高铝含量跨超晶格p型区实现无电子阻挡层的高效深紫外发光二极管","authors":"Xien Sang, Aoxiang Zhang, Xin Wang, Wenlan Ma, Fang Wang, Junjie Liu, Feng Yun, Yuhuai Liu","doi":"10.1021/acsami.5c15309","DOIUrl":null,"url":null,"abstract":"Deep ultraviolet light-emitting diodes (DUV-LEDs) face critical challenges such as poor hole injection and significant electron leakage, both of which severely limit their external quantum efficiency (EQE). This study possesses and simulates six DUV-LED structures featuring p-type superlattices with varying aluminum compositions using the SiLENSe module that integrates Schrödinger-Poisson and drift-diffusion models. Among them, structure F, which eliminates the conventional electron blocking layer (EBL) and incorporates a graded Al<sub>0.8</sub>Ga<sub>0.2</sub>N/Al<sub>0.6</sub>Ga<sub>0.4</sub>N superlattice, demonstrates the best performance. It achieves an EQE of 6.3% and a peak optical output power of 25 mW. Detailed analyses of band diagrams and carrier distributions confirm that the structure simultaneously enhances hole injection and effectively suppresses electron leakage. These improvements are attributed to the formation of stepped valence band profiles and reinforced electron barriers within the superlattice. This dual-function design highlights a viable and efficient strategy for advancing high-performance DUV-LEDs through p-type band engineering without relying on traditional EBLs.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"17 1","pages":""},"PeriodicalIF":8.2000,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High-Efficiency Deep Ultraviolet Light-Emitting Diodes without an Electron Blocking Layer Enabled by a High-Aluminum-Content Spanning Superlattice p-Type Region\",\"authors\":\"Xien Sang, Aoxiang Zhang, Xin Wang, Wenlan Ma, Fang Wang, Junjie Liu, Feng Yun, Yuhuai Liu\",\"doi\":\"10.1021/acsami.5c15309\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Deep ultraviolet light-emitting diodes (DUV-LEDs) face critical challenges such as poor hole injection and significant electron leakage, both of which severely limit their external quantum efficiency (EQE). This study possesses and simulates six DUV-LED structures featuring p-type superlattices with varying aluminum compositions using the SiLENSe module that integrates Schrödinger-Poisson and drift-diffusion models. Among them, structure F, which eliminates the conventional electron blocking layer (EBL) and incorporates a graded Al<sub>0.8</sub>Ga<sub>0.2</sub>N/Al<sub>0.6</sub>Ga<sub>0.4</sub>N superlattice, demonstrates the best performance. It achieves an EQE of 6.3% and a peak optical output power of 25 mW. Detailed analyses of band diagrams and carrier distributions confirm that the structure simultaneously enhances hole injection and effectively suppresses electron leakage. These improvements are attributed to the formation of stepped valence band profiles and reinforced electron barriers within the superlattice. This dual-function design highlights a viable and efficient strategy for advancing high-performance DUV-LEDs through p-type band engineering without relying on traditional EBLs.\",\"PeriodicalId\":5,\"journal\":{\"name\":\"ACS Applied Materials & Interfaces\",\"volume\":\"17 1\",\"pages\":\"\"},\"PeriodicalIF\":8.2000,\"publicationDate\":\"2025-10-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Materials & Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acsami.5c15309\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Materials & Interfaces","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsami.5c15309","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
High-Efficiency Deep Ultraviolet Light-Emitting Diodes without an Electron Blocking Layer Enabled by a High-Aluminum-Content Spanning Superlattice p-Type Region
Deep ultraviolet light-emitting diodes (DUV-LEDs) face critical challenges such as poor hole injection and significant electron leakage, both of which severely limit their external quantum efficiency (EQE). This study possesses and simulates six DUV-LED structures featuring p-type superlattices with varying aluminum compositions using the SiLENSe module that integrates Schrödinger-Poisson and drift-diffusion models. Among them, structure F, which eliminates the conventional electron blocking layer (EBL) and incorporates a graded Al0.8Ga0.2N/Al0.6Ga0.4N superlattice, demonstrates the best performance. It achieves an EQE of 6.3% and a peak optical output power of 25 mW. Detailed analyses of band diagrams and carrier distributions confirm that the structure simultaneously enhances hole injection and effectively suppresses electron leakage. These improvements are attributed to the formation of stepped valence band profiles and reinforced electron barriers within the superlattice. This dual-function design highlights a viable and efficient strategy for advancing high-performance DUV-LEDs through p-type band engineering without relying on traditional EBLs.
期刊介绍:
ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.