{"title":"搭建桥式双环脚手架","authors":"Stacey Brenner-Moyer","doi":"10.1038/s44160-025-00798-4","DOIUrl":null,"url":null,"abstract":"A catalytic asymmetric intramolecular reaction is developed for the [5+2] cycloaddition of oxidopyrylium ylides, enabled by chiral phosphoric acid organocatalysts, providing access to bridged bicyclic scaffolds.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"4 10","pages":"1178-1180"},"PeriodicalIF":20.0000,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Building bridged bicyclic scaffolds\",\"authors\":\"Stacey Brenner-Moyer\",\"doi\":\"10.1038/s44160-025-00798-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A catalytic asymmetric intramolecular reaction is developed for the [5+2] cycloaddition of oxidopyrylium ylides, enabled by chiral phosphoric acid organocatalysts, providing access to bridged bicyclic scaffolds.\",\"PeriodicalId\":74251,\"journal\":{\"name\":\"Nature synthesis\",\"volume\":\"4 10\",\"pages\":\"1178-1180\"},\"PeriodicalIF\":20.0000,\"publicationDate\":\"2025-05-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.nature.com/articles/s44160-025-00798-4\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"0\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s44160-025-00798-4","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A catalytic asymmetric intramolecular reaction is developed for the [5+2] cycloaddition of oxidopyrylium ylides, enabled by chiral phosphoric acid organocatalysts, providing access to bridged bicyclic scaffolds.
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