{"title":"低碳硫铝酸钙水泥新型超高性能混凝土的研制与性能评价","authors":"Zhiyao Ma, Xujiang Wang, Yonggang Yao, Zeyang Pan, Renjie Mi, Jingwei Li, Jiwen Liu, Jianyong Wang, Yanpeng Mao, Zhijuan Hu, Wenlong Wang","doi":"10.1617/s11527-025-02818-3","DOIUrl":null,"url":null,"abstract":"<div><p>Ultra-high performance concrete (UHPC) faces challenges in optimizing workability, strength, and durability while maintaining sustainability. Calcium sulfoaluminate (CSA) cement, known for its high early strength and low carbon footprint, offers a promising alternative binder. However, its application in UHPC requires further optimization to balance mechanical performance and shrinkage resistance. This study developed a novel UHPC using solid waste-based calcium sulfoaluminate cement (SCSA) and investigated the feasibility of substituting silica fume (SF) with steel slag micro powder (SSMP). The physical properties, hydration process, volume stability, microstructure and carbon footprint of the novel UHPC system were systematically examined. The results demonstrated that the SSMP enhances the mechanical strength of UHPC at all ages, with an 80% replacement increasing compressive strength by 25.9% at 3d, 18.8% at 7d, and 13.4% at 28d compared to the control group. XRD, TG, and MIP results indicate that SSMP further promotes hydration by generating C–S–H through its cementitious activity and pozzolanic reactions. Furthermore, when the SSMP replacement ratio does not exceed 40%, it effectively reduces the autogenous shrinkage of UHPC, addressing a key limitation of conventional UHPC. Microstructural observations show that the addition of SSMP reduces harmful pores, and enhances ettringite crystal interlocking. Moreover, carbon footprint analysis indicates that SCSA-UHPC is a greener material with lower carbon emissions, while the incorporation of SSMP as a replacement further reduces carbon footprint by utilizing solid waste. However, the SSMP content should be controlled, as excess content compromises workability and volume stability. These findings highlight the potential of SCSA-UHPC as a sustainable and high-performance material, providing new insights for low-carbon construction applications.</p></div>","PeriodicalId":691,"journal":{"name":"Materials and Structures","volume":"58 9","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development and performance evaluation of a novel ultra-high performance concrete based on low-carbon calcium sulfoaluminate cement\",\"authors\":\"Zhiyao Ma, Xujiang Wang, Yonggang Yao, Zeyang Pan, Renjie Mi, Jingwei Li, Jiwen Liu, Jianyong Wang, Yanpeng Mao, Zhijuan Hu, Wenlong Wang\",\"doi\":\"10.1617/s11527-025-02818-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Ultra-high performance concrete (UHPC) faces challenges in optimizing workability, strength, and durability while maintaining sustainability. Calcium sulfoaluminate (CSA) cement, known for its high early strength and low carbon footprint, offers a promising alternative binder. However, its application in UHPC requires further optimization to balance mechanical performance and shrinkage resistance. This study developed a novel UHPC using solid waste-based calcium sulfoaluminate cement (SCSA) and investigated the feasibility of substituting silica fume (SF) with steel slag micro powder (SSMP). The physical properties, hydration process, volume stability, microstructure and carbon footprint of the novel UHPC system were systematically examined. The results demonstrated that the SSMP enhances the mechanical strength of UHPC at all ages, with an 80% replacement increasing compressive strength by 25.9% at 3d, 18.8% at 7d, and 13.4% at 28d compared to the control group. XRD, TG, and MIP results indicate that SSMP further promotes hydration by generating C–S–H through its cementitious activity and pozzolanic reactions. Furthermore, when the SSMP replacement ratio does not exceed 40%, it effectively reduces the autogenous shrinkage of UHPC, addressing a key limitation of conventional UHPC. Microstructural observations show that the addition of SSMP reduces harmful pores, and enhances ettringite crystal interlocking. Moreover, carbon footprint analysis indicates that SCSA-UHPC is a greener material with lower carbon emissions, while the incorporation of SSMP as a replacement further reduces carbon footprint by utilizing solid waste. However, the SSMP content should be controlled, as excess content compromises workability and volume stability. These findings highlight the potential of SCSA-UHPC as a sustainable and high-performance material, providing new insights for low-carbon construction applications.</p></div>\",\"PeriodicalId\":691,\"journal\":{\"name\":\"Materials and Structures\",\"volume\":\"58 9\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-10-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials and Structures\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1617/s11527-025-02818-3\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CONSTRUCTION & BUILDING TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials and Structures","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1617/s11527-025-02818-3","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
Development and performance evaluation of a novel ultra-high performance concrete based on low-carbon calcium sulfoaluminate cement
Ultra-high performance concrete (UHPC) faces challenges in optimizing workability, strength, and durability while maintaining sustainability. Calcium sulfoaluminate (CSA) cement, known for its high early strength and low carbon footprint, offers a promising alternative binder. However, its application in UHPC requires further optimization to balance mechanical performance and shrinkage resistance. This study developed a novel UHPC using solid waste-based calcium sulfoaluminate cement (SCSA) and investigated the feasibility of substituting silica fume (SF) with steel slag micro powder (SSMP). The physical properties, hydration process, volume stability, microstructure and carbon footprint of the novel UHPC system were systematically examined. The results demonstrated that the SSMP enhances the mechanical strength of UHPC at all ages, with an 80% replacement increasing compressive strength by 25.9% at 3d, 18.8% at 7d, and 13.4% at 28d compared to the control group. XRD, TG, and MIP results indicate that SSMP further promotes hydration by generating C–S–H through its cementitious activity and pozzolanic reactions. Furthermore, when the SSMP replacement ratio does not exceed 40%, it effectively reduces the autogenous shrinkage of UHPC, addressing a key limitation of conventional UHPC. Microstructural observations show that the addition of SSMP reduces harmful pores, and enhances ettringite crystal interlocking. Moreover, carbon footprint analysis indicates that SCSA-UHPC is a greener material with lower carbon emissions, while the incorporation of SSMP as a replacement further reduces carbon footprint by utilizing solid waste. However, the SSMP content should be controlled, as excess content compromises workability and volume stability. These findings highlight the potential of SCSA-UHPC as a sustainable and high-performance material, providing new insights for low-carbon construction applications.
期刊介绍:
Materials and Structures, the flagship publication of the International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM), provides a unique international and interdisciplinary forum for new research findings on the performance of construction materials. A leader in cutting-edge research, the journal is dedicated to the publication of high quality papers examining the fundamental properties of building materials, their characterization and processing techniques, modeling, standardization of test methods, and the application of research results in building and civil engineering. Materials and Structures also publishes comprehensive reports prepared by the RILEM’s technical committees.