提高透气性和防污性的聚砜复合膜去除染料的研究

IF 4 3区 化学 Q2 POLYMER SCIENCE
Shwetha Kodange, Srilatha Rao, Prashanth Gopala Krishna, Mahesh Padaki, Sk Safikul Islam, Suryasarathi Bose
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引用次数: 0

摘要

聚砜(Psf)膜以其优异的机械强度、热稳定性和耐化学性被广泛应用于膜分离工艺中。然而,它们容易受到膜污染,随后呈现出效率下降。为了解决这个问题,Psf膜经常被修改。本研究旨在将SBAL配合物(银包覆在BSA上)加入到Psf基质中,制备一种新型SBAL/Psf复合膜,以增强膜分离过程,减少膜污染。利用FT-IR、TGA、FESEM、CA和zeta电位对所制备的配合物和膜进行了表征。随后,评估了其在不同压力下的渗透率、吸水率和孔隙度。SBAL配合物的加入提高了Psf膜的热稳定性(高达450°C)、孔隙率(76.72%)、亲水性(56.87°)和吸水性(73.24%)。并对不同压力下膜对EBT和MB染料的去除率进行了评价。最后,通过将所生产的膜暴露于含有杂质混合物的饲料溶液中,该研究强调了其防污特性。SBAL复合物浓度最高的Psf膜不可逆结垢率和总结垢率均较低,具有较好的防污能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Incapacitating the challenges of dye removal using polysulfone composite membrane with improved permeability and antifouling study

The polysulfone (Psf) membranes are widely used in membrane separation processes due to their excellent mechanical strength, thermal stability and chemical resistance. Nevertheless, they are susceptible for membrane fouling and subsequently presents decreased efficiency. To address this issue, Psf membranes are often modified. The study aims to prepare a novel SBAL/Psf composite membrane by incorporating SBAL complex (Ag capped on BSA) into the Psf matrix which enhances the membrane separation process and reduces the membrane fouling. The prepared complex and the membranes were characterized using FT-IR, TGA, FESEM, CA and zeta potential. Later, assessed for its permeability at various pressures, water uptake and porosity. The thermal stability (up to 450 °C) porosity (76.72%) hydrophilicity (56.87°) and water uptake (73.24%) were improved compared with respect to bare Psf membrane by the addition of the SBAL complex. Also, the membranes were evaluated for the effective removal of EBT and MB dyes at different pressures. Lastly, by exposing the produced membranes to a feed solution that contains a foulant mixture, the study emphasizes the antifouling qualities. The Psf membrane with the highest concentration of SBAL complex showed low irreversible fouling and total fouling, thus indicating its remarkable antifouling capability.

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来源期刊
Polymer Bulletin
Polymer Bulletin 化学-高分子科学
CiteScore
6.00
自引率
6.20%
发文量
0
审稿时长
5.5 months
期刊介绍: "Polymer Bulletin" is a comprehensive academic journal on polymer science founded in 1988. It was founded under the initiative of the late Mr. Wang Baoren, a famous Chinese chemist and educator. This journal is co-sponsored by the Chinese Chemical Society, the Institute of Chemistry, and the Chinese Academy of Sciences and is supervised by the China Association for Science and Technology. It is a core journal and is publicly distributed at home and abroad. "Polymer Bulletin" is a monthly magazine with multiple columns, including a project application guide, outlook, review, research papers, highlight reviews, polymer education and teaching, information sharing, interviews, polymer science popularization, etc. The journal is included in the CSCD Chinese Science Citation Database. It serves as the source journal for Chinese scientific and technological paper statistics and the source journal of Peking University's "Overview of Chinese Core Journals."
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