{"title":"用功能化蒽醌-聚氨酯混合涂层改性无机玄武岩显色织物:优异的耐磨性和电磁干扰屏蔽","authors":"Mengyuan Qi, , , Guowei Xiao, , , Sen Chen, , , Xiaoyan Wang, , , Anyang Duan, , , Jinmei Du, , , Dagang Miao, , , Hongying Yang*, , and , Changhai Xu*, ","doi":"10.1021/acsapm.5c03050","DOIUrl":null,"url":null,"abstract":"<p >Basalt fibers (BFs) exhibit promising applications in the textile industry due to their mechanical properties, temperature resistance, and corrosion resistance; however, they are still primarily limited by fiber fracture and the availability of a single color. In this work, a functionalized anthraquinone polyurethane (WAPU) coating was used to modify basalt fabrics to prepare an exceptional wear resistance and electromagnetically shielded purple basalt fabric with a three-dimensional (3D) network embedded structure. The treated fabric exhibited a high fastness purple color (fastness level 4) covered by WAPU coating; significant tensile strength (44.66%) and tear strength (137.17%) were also achieved. The wear resistance was demonstrated as the treated yarn on the fabric surface broke only after cycling for 25,000 cycles, increasing cycles by 1462.5% relative to the BF. The thermalhydro comfort of the fabric was maintained after treatment. In addition, this WAPU/Ag coated fabric also showcased EMI shielding performance (41.1 dB) in the X-band range. This work advances the application process of inorganic basalt fibers in the clothing textile field and provides application scenarios for inorganic functionalized textiles.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 19","pages":"13415–13427"},"PeriodicalIF":4.7000,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Modification of a Chromogenic Inorganic Basalt Fabric via a Functionalized Anthraquinone Polyurethane Mixed Coating: Exceptional Wear Resistance and EMI Shielding\",\"authors\":\"Mengyuan Qi, , , Guowei Xiao, , , Sen Chen, , , Xiaoyan Wang, , , Anyang Duan, , , Jinmei Du, , , Dagang Miao, , , Hongying Yang*, , and , Changhai Xu*, \",\"doi\":\"10.1021/acsapm.5c03050\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Basalt fibers (BFs) exhibit promising applications in the textile industry due to their mechanical properties, temperature resistance, and corrosion resistance; however, they are still primarily limited by fiber fracture and the availability of a single color. In this work, a functionalized anthraquinone polyurethane (WAPU) coating was used to modify basalt fabrics to prepare an exceptional wear resistance and electromagnetically shielded purple basalt fabric with a three-dimensional (3D) network embedded structure. The treated fabric exhibited a high fastness purple color (fastness level 4) covered by WAPU coating; significant tensile strength (44.66%) and tear strength (137.17%) were also achieved. The wear resistance was demonstrated as the treated yarn on the fabric surface broke only after cycling for 25,000 cycles, increasing cycles by 1462.5% relative to the BF. The thermalhydro comfort of the fabric was maintained after treatment. In addition, this WAPU/Ag coated fabric also showcased EMI shielding performance (41.1 dB) in the X-band range. This work advances the application process of inorganic basalt fibers in the clothing textile field and provides application scenarios for inorganic functionalized textiles.</p>\",\"PeriodicalId\":7,\"journal\":{\"name\":\"ACS Applied Polymer Materials\",\"volume\":\"7 19\",\"pages\":\"13415–13427\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-09-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Polymer Materials\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsapm.5c03050\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Polymer Materials","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsapm.5c03050","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Modification of a Chromogenic Inorganic Basalt Fabric via a Functionalized Anthraquinone Polyurethane Mixed Coating: Exceptional Wear Resistance and EMI Shielding
Basalt fibers (BFs) exhibit promising applications in the textile industry due to their mechanical properties, temperature resistance, and corrosion resistance; however, they are still primarily limited by fiber fracture and the availability of a single color. In this work, a functionalized anthraquinone polyurethane (WAPU) coating was used to modify basalt fabrics to prepare an exceptional wear resistance and electromagnetically shielded purple basalt fabric with a three-dimensional (3D) network embedded structure. The treated fabric exhibited a high fastness purple color (fastness level 4) covered by WAPU coating; significant tensile strength (44.66%) and tear strength (137.17%) were also achieved. The wear resistance was demonstrated as the treated yarn on the fabric surface broke only after cycling for 25,000 cycles, increasing cycles by 1462.5% relative to the BF. The thermalhydro comfort of the fabric was maintained after treatment. In addition, this WAPU/Ag coated fabric also showcased EMI shielding performance (41.1 dB) in the X-band range. This work advances the application process of inorganic basalt fibers in the clothing textile field and provides application scenarios for inorganic functionalized textiles.
期刊介绍:
ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers.
The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.