挤压多孔蛋白质-木质纤维素共混物作为一次性吸收塑料的完全生物基替代品

IF 4.7 2区 化学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Athanasios Latras*, , , Pamela F. M. Pereira, , , Amparo Jiménez-Quero, , , Karin Odelius, , , Mercedes Jiménez-Rosado, , and , Antonio J. Capezza*, 
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引用次数: 0

摘要

可持续技术使可降解的一次性塑料(sup)的生产能够用于各种应用。然而,环保,多孔的一次性吸收剂仍然缺乏合成选择的竞争性功能。在这项工作中,我们报道了从整合蛋白质和木质纤维素残留物中提取的全生物聚合物基多孔吸附剂的连续挤出,所有这些都来自生物质废物。结果表明,与仅加入食品工业的木质纤维素副产品燕麦壳相比,挤压材料的盐吸收能力提高了1.5倍。通过在燕麦壳和麦麸上加入脱木质素步骤,吸收率进一步提高了2倍,这表明生物质化学对提高材料吸收率的重要性。在这里,从食物垃圾中添加20%的角蛋白纤维,将材料的吸收率提高到6.5 g/g,并能够在其结构中保留2 g/g的盐水溶液,这也是迄今为止报道的挤出蛋白质配方的最高值。这项工作推进多孔吸收材料的发展具有竞争力的性能,利用工业方法和升级回收低估的生物质废物为可持续消费产品。引入多孔生物聚合物材料作为卫生和卫生行业中使用的合成材料的替代品,确保安全分子回归自然,为无微塑料、一次性、多孔吸收剂铺平道路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Extruded Porous Protein–Lignocellulosic Blends as Fully Bio-Based Alternative to Single-Use Absorbent Plastics

Sustainable technologies have enabled the production of degradable single-use plastics (SUPs) for various applications. However, environmentally friendly, porous disposable absorbents still lack the competitive functionality of synthetic options. In this work, we report the continuous extrusion of fully biopolymer-based porous absorbents derived from integrated proteins and lignocellulosic residues, all sourced from biomass waste. The results show that the saline absorption capacity of the extruded materials increases 1.5 times compared to the reference solely by including oat husk, a lignocellulosic byproduct from the food industry. The absorption was further improved 2 times by including a delignification step on the oat husk and wheat bran, demonstrating the importance of the biomass’s chemistry in increasing the material’s absorption. Here, the addition of 20 wt % of Keratin fibers from food waste increases the material’s absorbency to 6.5 g/g, with the ability to retain 2 g/g of the saline solution in its structure, which is also the highest reported value for extruded protein-based formulations so far. This work advances the development of porous absorbent materials with competitive performance, utilizing industrial methods and upcycling undervalued biomass waste into sustainable consumer products. Introducing porous biopolymer-based materials as alternatives to synthetic counterparts used in the hygiene and sanitary industries ensures the return of safe molecules to nature, paving the way for microplastic-free, single-use, porous absorbents.

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来源期刊
CiteScore
7.20
自引率
6.00%
发文量
810
期刊介绍: ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.
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