离子液体基夹带剂反应萃取精馏可持续分离醋酸烯丙酯-烯丙醇-水体系的多目标优化

IF 9 1区工程技术 Q1 ENGINEERING, CHEMICAL

Separation and Purification Technology Pub Date : 2025-10-06 DOI:10.1016/j.seppur.2025.135438

Wenxuan Zhao, Wenna Liu, Ying Xu, Huairong Zhou, Zhaoyou Zhu, Yinglong Wang, Peizhe Cui, Guoxuan Li

{"title":"离子液体基夹带剂反应萃取精馏可持续分离醋酸烯丙酯-烯丙醇-水体系的多目标优化","authors":"Wenxuan Zhao, Wenna Liu, Ying Xu, Huairong Zhou, Zhaoyou Zhu, Yinglong Wang, Peizhe Cui, Guoxuan Li","doi":"10.1016/j.seppur.2025.135438","DOIUrl":null,"url":null,"abstract":"This study focuses on the separation problem of the allyl acetate/allyl alcohol/H2O azeotropic system. With the help of extractive distillation and reactive extractive distillation technology, the system is optimized in combination with thermodynamic analysis and process intensification strategy. Based on the COSMO-SAC model, ionic liquids entrainers are screened, and six candidate entrainers such as [PMIM] [NO3] are determined by comprehensive evaluation, and their compatibility with the intermolecular interaction energy of the system is verified by quantum chemical calculation. The multi-objective optimization algorithm is used to determine [MIM] [NO3] as the optimal entrainer. Heat-integration and heat pump-assisted heat integration technology enhanced processes are introduced. After Economy-Environment-Exergy-Energy verification, the heat pump-assisted heat integration extractive distillation process is superior to the heat-integrated assisted extractive distillation. Compared with the traditional extractive distillation process, the annual total cost is reduced by 12.66 % and gas emissions are reduced by 30.19 %. Further considering the exothermic reaction of ethylene oxide and H2O, combined with the heat integrated enhanced process, the annual total cost is reduced by 17.61 % and gas emissions are reduced by 60.38 %. It is finally determined that the heat integrated assisted reactive extractive distillation process shows significant advantages in technical economy and environmental sustainability, providing an innovative solution for the clean separation of azeotropic systems.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"8 1","pages":"135438"},"PeriodicalIF":9.0000,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multi-objective optimization of reactive extractive distillation with ionic liquid-based entrainer for sustainable separation of the Allyl Acetate-Allyl Alcohol-Water system\",\"authors\":\"Wenxuan Zhao, Wenna Liu, Ying Xu, Huairong Zhou, Zhaoyou Zhu, Yinglong Wang, Peizhe Cui, Guoxuan Li\",\"doi\":\"10.1016/j.seppur.2025.135438\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study focuses on the separation problem of the allyl acetate/allyl alcohol/H2O azeotropic system. With the help of extractive distillation and reactive extractive distillation technology, the system is optimized in combination with thermodynamic analysis and process intensification strategy. Based on the COSMO-SAC model, ionic liquids entrainers are screened, and six candidate entrainers such as [PMIM] [NO3] are determined by comprehensive evaluation, and their compatibility with the intermolecular interaction energy of the system is verified by quantum chemical calculation. The multi-objective optimization algorithm is used to determine [MIM] [NO3] as the optimal entrainer. Heat-integration and heat pump-assisted heat integration technology enhanced processes are introduced. After Economy-Environment-Exergy-Energy verification, the heat pump-assisted heat integration extractive distillation process is superior to the heat-integrated assisted extractive distillation. Compared with the traditional extractive distillation process, the annual total cost is reduced by 12.66 % and gas emissions are reduced by 30.19 %. Further considering the exothermic reaction of ethylene oxide and H2O, combined with the heat integrated enhanced process, the annual total cost is reduced by 17.61 % and gas emissions are reduced by 60.38 %. It is finally determined that the heat integrated assisted reactive extractive distillation process shows significant advantages in technical economy and environmental sustainability, providing an innovative solution for the clean separation of azeotropic systems.\",\"PeriodicalId\":427,\"journal\":{\"name\":\"Separation and Purification Technology\",\"volume\":\"8 1\",\"pages\":\"135438\"},\"PeriodicalIF\":9.0000,\"publicationDate\":\"2025-10-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Separation and Purification Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1016/j.seppur.2025.135438\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Separation and Purification Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1016/j.seppur.2025.135438","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}

引用次数: 0

摘要

研究了醋酸烯丙酯/烯丙醇/水共沸体系的分离问题。借助萃取精馏和反应萃取精馏技术，结合热力学分析和工艺强化策略对系统进行优化。基于cosmos - sac模型对离子液体夹带剂进行筛选，通过综合评价确定了[PMIM] [NO3]等6种候选夹带剂，并通过量子化学计算验证了它们与体系分子间相互作用能的相容性。采用多目标优化算法确定[MIM] [NO3]为最优夹带器。介绍了热集成和热泵辅助热集成技术的强化工艺。经经济-环境-能源-能源验证，热泵辅助热集成萃取精馏工艺优于热集成辅助萃取精馏工艺。与传统萃取精馏工艺相比，年总成本降低12.66%，气体排放量减少30.19%。进一步考虑环氧乙烷与H2O的放热反应，结合热集成强化工艺，年总成本降低17.61%，气体排放量减少60.38%。结果表明，热集成辅助反应萃取精馏工艺具有显著的技术经济和环境可持续性优势，为共沸体系的清洁分离提供了一种创新的解决方案。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Multi-objective optimization of reactive extractive distillation with ionic liquid-based entrainer for sustainable separation of the Allyl Acetate-Allyl Alcohol-Water system

This study focuses on the separation problem of the allyl acetate/allyl alcohol/H₂O azeotropic system. With the help of extractive distillation and reactive extractive distillation technology, the system is optimized in combination with thermodynamic analysis and process intensification strategy. Based on the COSMO-SAC model, ionic liquids entrainers are screened, and six candidate entrainers such as [PMIM] [NO₃] are determined by comprehensive evaluation, and their compatibility with the intermolecular interaction energy of the system is verified by quantum chemical calculation. The multi-objective optimization algorithm is used to determine [MIM] [NO₃] as the optimal entrainer. Heat-integration and heat pump-assisted heat integration technology enhanced processes are introduced. After Economy-Environment-Exergy-Energy verification, the heat pump-assisted heat integration extractive distillation process is superior to the heat-integrated assisted extractive distillation. Compared with the traditional extractive distillation process, the annual total cost is reduced by 12.66 % and gas emissions are reduced by 30.19 %. Further considering the exothermic reaction of ethylene oxide and H₂O, combined with the heat integrated enhanced process, the annual total cost is reduced by 17.61 % and gas emissions are reduced by 60.38 %. It is finally determined that the heat integrated assisted reactive extractive distillation process shows significant advantages in technical economy and environmental sustainability, providing an innovative solution for the clean separation of azeotropic systems.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Separation and Purification Technology 工程技术-工程：化工

CiteScore

14.00

自引率

12.80%

发文量

2347

审稿时长

43 days

期刊介绍： Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.