{"title":"一种用于全光谱照明的掺杂Mn4+远红发光荧光粉。","authors":"Chunchun Chen, , , Zeyu Lyu*, , , Zheng Lu, , , Xiaowei Zhang, , , Dashuai Sun, , , Shuai Wei, , , Fang Guan, , and , Hongpeng You*, ","doi":"10.1021/acs.inorgchem.5c03887","DOIUrl":null,"url":null,"abstract":"<p >Mn<sup>4+</sup>-doped oxide red phosphors exhibit significant potential in full-spectrum lighting and plant growth lighting. Far-red emitting CaLuAlO<sub>4</sub>:Mn<sup>4+</sup> phosphor was obtained by a high-temperature solid-phase method. In this structure, Mn<sup>4+</sup> occupies the position of [AlO<sub>6</sub>], and exhibits two broad excitation bands in the 250–600 nm range. Upon 365 nm near-ultraviolet excitation, this phosphor exhibits far-red emission near 707 nm. Its internal quantum efficiency and absorptivity were measured to be 55.04% and 81.48%, respectively. CaLuAlO<sub>4</sub>:Mn<sup>4+</sup> can compensate for the far-red emission deficiency of WLEDs, attaining a low correlated color temperature (CCT = 3548 K) and a high color rendering index (<i>R</i><sub>a</sub> = 96.5). Plant growth experiments using packaged far-red LED verified its positive effects on plant growth. These results demonstrate the potential of CaLuAlO<sub>4</sub>:Mn<sup>4+</sup> red phosphors for applications in full-spectrum lighting and plant growth lighting.</p>","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 41","pages":"20825–20831"},"PeriodicalIF":4.7000,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Mn4+-Doped Far-Red-Emitting Phosphor toward Full-Spectrum Lighting\",\"authors\":\"Chunchun Chen, , , Zeyu Lyu*, , , Zheng Lu, , , Xiaowei Zhang, , , Dashuai Sun, , , Shuai Wei, , , Fang Guan, , and , Hongpeng You*, \",\"doi\":\"10.1021/acs.inorgchem.5c03887\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Mn<sup>4+</sup>-doped oxide red phosphors exhibit significant potential in full-spectrum lighting and plant growth lighting. Far-red emitting CaLuAlO<sub>4</sub>:Mn<sup>4+</sup> phosphor was obtained by a high-temperature solid-phase method. In this structure, Mn<sup>4+</sup> occupies the position of [AlO<sub>6</sub>], and exhibits two broad excitation bands in the 250–600 nm range. Upon 365 nm near-ultraviolet excitation, this phosphor exhibits far-red emission near 707 nm. Its internal quantum efficiency and absorptivity were measured to be 55.04% and 81.48%, respectively. CaLuAlO<sub>4</sub>:Mn<sup>4+</sup> can compensate for the far-red emission deficiency of WLEDs, attaining a low correlated color temperature (CCT = 3548 K) and a high color rendering index (<i>R</i><sub>a</sub> = 96.5). Plant growth experiments using packaged far-red LED verified its positive effects on plant growth. These results demonstrate the potential of CaLuAlO<sub>4</sub>:Mn<sup>4+</sup> red phosphors for applications in full-spectrum lighting and plant growth lighting.</p>\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\"64 41\",\"pages\":\"20825–20831\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-10-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.inorgchem.5c03887\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.inorgchem.5c03887","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
A Mn4+-Doped Far-Red-Emitting Phosphor toward Full-Spectrum Lighting
Mn4+-doped oxide red phosphors exhibit significant potential in full-spectrum lighting and plant growth lighting. Far-red emitting CaLuAlO4:Mn4+ phosphor was obtained by a high-temperature solid-phase method. In this structure, Mn4+ occupies the position of [AlO6], and exhibits two broad excitation bands in the 250–600 nm range. Upon 365 nm near-ultraviolet excitation, this phosphor exhibits far-red emission near 707 nm. Its internal quantum efficiency and absorptivity were measured to be 55.04% and 81.48%, respectively. CaLuAlO4:Mn4+ can compensate for the far-red emission deficiency of WLEDs, attaining a low correlated color temperature (CCT = 3548 K) and a high color rendering index (Ra = 96.5). Plant growth experiments using packaged far-red LED verified its positive effects on plant growth. These results demonstrate the potential of CaLuAlO4:Mn4+ red phosphors for applications in full-spectrum lighting and plant growth lighting.
期刊介绍：
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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