活性炭负载NiO-CuO-ZnO三元金属氧化物光催化剂的简易合成及h2o2辅助降解毒死蜱

IF 2.5 4区 化学 Q2 Engineering
Nadeem Raza, Abdullah Jan, Mostafa E. Salem, Anis Ahmad Chaudhary, Fawad Ahmad
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引用次数: 0

摘要

农药在全球范围内的广泛生产、使用和处置,由于其生物积累和生物持久性,引起了人们对人类和动物健康的关注。近年来,金属氧化物基光催化技术因其可行性、成本效益和更快的降解速度而引起了众多研究人员的关注。为了提高降解效率,人们对金属氧化物基光催化降解进行了各种改性研究,如二元、三元或金属/非金属掺杂金属氧化物光催化剂。研究了在紫外和日光照射下,三元金属氧化物(NiO-CuO-ZnO)光催化剂对水中毒死蜱的降解作用。考察了反应时间、pH、氧化物质(H2O2)、毒死蜱初始浓度、紫外/日光照射等参数对毒死蜱降解的影响。活性炭负载的NiO-CuO-ZnO光催化剂在45 min的反应时间后,降解率有所提高。采用紫外可见分光光度法对毒死蜱的降解进行了分析。为了维护环境的安全,需要更多的研究来实现快速和最大程度的恶化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Facile synthesis of charcoal-loaded NiO–CuO–ZnO ternary metal oxide photocatalyst and H2O2-assisted degradation of chlorpyrifos

Facile synthesis of charcoal-loaded NiO–CuO–ZnO ternary metal oxide photocatalyst and H2O2-assisted degradation of chlorpyrifos

The widespread manufacturing, use, and disposal of pesticides around the globe raise concerns about both human and animal health because of their bioaccumulating and biopersistent properties. A growing technology for the elimination of pesticides in aqueous media, metal oxide-based photocatalysis has attracted the attention of numerous researchers in recent years because of its viability, cost-effectiveness, and faster rate of degradation. In order to increase the efficiency of degradation, metal oxide-based photocatalytic degradation has been researched with various modifications, such as binary, ternary, or metal/non-metal-doped metal oxide photocatalysts. Chlorpyrifos degradation in aqueous medium by ternary metal oxide (NiO–CuO–ZnO) photocatalyst under UV and sunlight irradiations was investigated in this research. The influence of reaction parameters such as reaction time, pH, influence of oxidizing specie (H2O2), initial chlorpyrifos concentration, and UV/sunlight irradiation on chlorpyrifos degradation was studied. Improved degradation percentage was showed by charcoal-loaded NiO–CuO–ZnO photocatalyst after 45-min reaction time. UV–visible spectrophotometer was used to analyze the degradation of chlorpyrifos. To maintain the environment’s safety, more research is necessary to achieve rapid and maximal deterioration.

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来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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