左旋葡萄糖酮与α-碳乙氧基环十二酮加合物在手性螺环丁酮合成中的应用

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-10-07 DOI:10.1134/S107036322560417X

Yu. S. Galimova, Sh. M. Salikhov, L. Kh. Faizullina

引用次数: 0

摘要

以左旋葡萄糖酮和α-碳乙氧基环十二酮的非对映体Michael加合物为基础，采用6步法合成了手性螺环丁酮，总收率为16%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Michael Adduct of Levoglucosenone and α-Carboethoxycyclododecanone in the Synthesis of a Chiral Spirocyclobutanone

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Michael Adduct of Levoglucosenone and α-Carboethoxycyclododecanone in the Synthesis of a Chiral Spirocyclobutanone

Based on the diastereomeric Michael adducts of levoglucosenone and α-carboethoxycyclododecanone, a 6-step synthesis of a chiral spirocyclobutanone with an overall yield of 16% was developed.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.