Z. Abdul Vaheith, K. Suganya, K. S. Radha, Ehab El Sayed Massoud, K. SenthilKannan
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引用次数: 0
摘要
采用Sankaranarayana-Ramasamy (SR)法制备了硫氰酸锰汞晶体(MMTC)。在纯MMTC的基础上,通过高压和高温得到150尺度的MMTC结晶材料,进一步称为MMTC150S。MMTC150缩放晶体的晶格参数为a = 11.3199(3), b = 11.3199(3), c = 4.2755(5) Å。通过FITR研究确定了MMTC150S鳞片材料的官能团。材料的压电电荷系数为4.6 pC/N,范围为50-300 Hz。分析了红、蓝LED的效率,并报道了其灵敏度。MMTC150S晶体,其输出频率是输入频率的2.19倍,单位为Hz,用于电子领域。MMTC150S晶体的电子滤波器内流范围为3.1269微米。MMTC150S的荧光研究截止范围为267 nm。从tac的图中得到的光子应用和吸光度数据值分别为4.64、4.6441 eV。荧光发射为492 nm,带隙值为2.5203 eV,比纯MMTC高。MMTC150S晶体具有较低的介电常数,在光子学、电学和非线性光学(NLO)等领域具有广泛的应用价值。
Synthesis and Analysis of Shocked 150 Scaling Impacted on Manganese Mercury Thiocyanate Crystals for Spectral, Interactions, Electronic, Piezoelectric, Projective Displays and Sensor Utilities Correlated with Macro-MMTC
The manganese mercury thiocyanate crystal (MMTC) crystalline material was synthesized by the Sankaranarayana–Ramasamy (SR) method. The 150 scaled MMTC crystalline material was obtained by high pressure and temperature on pure MMTC, is further referred as MMTC150S. The lattice parameters of the MMTC150 scaled crystal are a = 11.3199(3), b = 11.3199(3), and c = 4.2755(5) Å. The functional groups of MMTC150S scaled material were identified by the FITR study. The piezoelectric charge coefficient of the material is 4.6 pC/N, the range starting from 50–300 Hz. The red, blue LED efficiency is analyzed, its sensitivity were reported. The MMTC150S crystal, the output frequency is 2.19 times than that of the input frequency value in Hz is used in electronic sectors. The electronic filter influx range as 3.1269 microns for MMTC150S crystal. The fluorescence studies of MMTC150S cut-off range 267 nm. The photonic application and absorbance data values are 4.64, 4.6441 eV confirmed from the from Tauc’s plot. The fluorescence emission is 492 nm, this gives a band gap value of 2.5203 eV, which is more than pure MMTC. The dielectric nature of MMTC150S crystal has a low value of the dielectric constant which confirms their utility of the crystalline specimen in photonics, electro-optics and in nonlinear optics (NLO).
期刊介绍:
Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.