Xianfei Xie, Sheng Wang, Danqiang Huang, Jianfeng Dai, Qing Wang
{"title":"轻质花状氮掺杂碳材料实现高效电磁波吸收","authors":"Xianfei Xie, Sheng Wang, Danqiang Huang, Jianfeng Dai, Qing Wang","doi":"10.1007/s42823-025-00937-z","DOIUrl":null,"url":null,"abstract":"<div><p>Structural design and element doping are the research hotspots in the preparation of lightweight absorbers with high absorption performance and low filling rate<b>.</b> This study employs different temperature carbonization and etching techniques to prepare the structure of hollow nitrogen-doped carbon flowers (HNC) and evaluate their microwave absorption performance. At an ultra-low filler loading of 5 wt.%, the microwave absorption intensity of HNC-800 remains stable at -50 dB with a thickness of 3.2 mm. It is noteworthy that the HNC-800 achieved the broadest effective absorption frequency band at a matching thickness of 2 mm, with a bandwidth of 5.36 GHz (ranging from 12.4 to 17.76 GHz). Such remarkable broadband and reflection loss performance can be attributed to the synergistic effects of the hollow porous network structure, interface polarization, and dipole relaxation mechanisms. More significantly, the reduction of the radar cross-section (RCS) amounts to as much as 31.67 dB m<sup>2</sup>, and it has been attested to possess excellent adsorption efficacy in practical application scenarios. HNC-800, as an absorbing material, holds potential for broad application prospects.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 5","pages":"2447 - 2458"},"PeriodicalIF":5.8000,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Lightweight flower-like nitrogen-doped carbon materials achieve efficient electromagnetic wave absorption\",\"authors\":\"Xianfei Xie, Sheng Wang, Danqiang Huang, Jianfeng Dai, Qing Wang\",\"doi\":\"10.1007/s42823-025-00937-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Structural design and element doping are the research hotspots in the preparation of lightweight absorbers with high absorption performance and low filling rate<b>.</b> This study employs different temperature carbonization and etching techniques to prepare the structure of hollow nitrogen-doped carbon flowers (HNC) and evaluate their microwave absorption performance. At an ultra-low filler loading of 5 wt.%, the microwave absorption intensity of HNC-800 remains stable at -50 dB with a thickness of 3.2 mm. It is noteworthy that the HNC-800 achieved the broadest effective absorption frequency band at a matching thickness of 2 mm, with a bandwidth of 5.36 GHz (ranging from 12.4 to 17.76 GHz). Such remarkable broadband and reflection loss performance can be attributed to the synergistic effects of the hollow porous network structure, interface polarization, and dipole relaxation mechanisms. More significantly, the reduction of the radar cross-section (RCS) amounts to as much as 31.67 dB m<sup>2</sup>, and it has been attested to possess excellent adsorption efficacy in practical application scenarios. HNC-800, as an absorbing material, holds potential for broad application prospects.</p></div>\",\"PeriodicalId\":506,\"journal\":{\"name\":\"Carbon Letters\",\"volume\":\"35 5\",\"pages\":\"2447 - 2458\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-06-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s42823-025-00937-z\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s42823-025-00937-z","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Structural design and element doping are the research hotspots in the preparation of lightweight absorbers with high absorption performance and low filling rate. This study employs different temperature carbonization and etching techniques to prepare the structure of hollow nitrogen-doped carbon flowers (HNC) and evaluate their microwave absorption performance. At an ultra-low filler loading of 5 wt.%, the microwave absorption intensity of HNC-800 remains stable at -50 dB with a thickness of 3.2 mm. It is noteworthy that the HNC-800 achieved the broadest effective absorption frequency band at a matching thickness of 2 mm, with a bandwidth of 5.36 GHz (ranging from 12.4 to 17.76 GHz). Such remarkable broadband and reflection loss performance can be attributed to the synergistic effects of the hollow porous network structure, interface polarization, and dipole relaxation mechanisms. More significantly, the reduction of the radar cross-section (RCS) amounts to as much as 31.67 dB m2, and it has been attested to possess excellent adsorption efficacy in practical application scenarios. HNC-800, as an absorbing material, holds potential for broad application prospects.
期刊介绍:
Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.