芳香n -甲基n -杂化Corrole及其有机铜（III）配合物位置异构体的定向合成

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-10-06 DOI:10.1039/d5cc05372b

Harapriya Rath, Anirban Panua, Gunasekaran Velmurugan, Peter Comba

引用次数: 0

摘要

我们报道了合成、光谱分析和固态结构证据的芳香b[18] n -混乱的corrole具有可见光-近红外吸收的前所未有的位置异构体。铜金属化生成了有机铜（III）配合物，并保留了芳香性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Targeted Synthesis of a Positional isomer of Aromatic N-methyl N-confused Corrole and its Organocopper(III) complex

We report the synthesis, spectroscopic analyses and solid-state structural evidence of an unprecedented positional isomer of aromatic [18] N-confused corrole exhibiting vis-NIR absorption. The copper metalation led to an organo-copper(III) complex with preserved aromaticity.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.