M.A. Mintairov, V.V. Evstropov, D.A. Malevsky, P.V. Pokrovskii, N. Yu Davidyk, N.A. Kalyuzhnyy
{"title":"温度依赖曲线法测定LED内部量子效率","authors":"M.A. Mintairov, V.V. Evstropov, D.A. Malevsky, P.V. Pokrovskii, N. Yu Davidyk, N.A. Kalyuzhnyy","doi":"10.1016/j.jlumin.2025.121573","DOIUrl":null,"url":null,"abstract":"<div><div>A new method for determining the internal quantum efficiency (IQE) of band-to-band luminescence of a light-emitting diodes (LED) is proposed and considered. The IQE value is represented by the product of <em>g</em> and <em>θ</em> values, where g is the band-to-band recombination fraction of the total current and <em>θ</em> is the internal quantum yield of band-to-band recombination, i.e. the fraction of the radiative part of this channel. As shown in the paper, <em>g</em> value can be determined from the experimental IV-curve. The <em>θ</em> value is determined based on the model of the band-to-band channel as a recombination defect. With decreasing temperature, the nonradiative part of the band-to-band channel critically decreases, while the radiative part does not depend on temperature. At ultimately low temperatures, the internal quantum yield of the channel tends to unity. This property allows determining <em>θ</em> values for any temperature using the analysis of the experimental temperature dependence of the electroluminescence intensity. Determining <em>g</em> and <em>θ</em> values allows finding IQE for any temperature (including room temperature). The method has been approved for LEDs fabricated on the basis of MOVPE grown AlGaAs heterostructures with InGaAs multiple quantum wells emitting at wavelength of on 850, 910 and 940 nm. All LEDs have shown maximal IQE of about 80 %–90 %.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"288 ","pages":"Article 121573"},"PeriodicalIF":3.6000,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Temperature depended IV-curve method for determining LED internal quantum efficiency\",\"authors\":\"M.A. Mintairov, V.V. Evstropov, D.A. Malevsky, P.V. Pokrovskii, N. Yu Davidyk, N.A. Kalyuzhnyy\",\"doi\":\"10.1016/j.jlumin.2025.121573\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A new method for determining the internal quantum efficiency (IQE) of band-to-band luminescence of a light-emitting diodes (LED) is proposed and considered. The IQE value is represented by the product of <em>g</em> and <em>θ</em> values, where g is the band-to-band recombination fraction of the total current and <em>θ</em> is the internal quantum yield of band-to-band recombination, i.e. the fraction of the radiative part of this channel. As shown in the paper, <em>g</em> value can be determined from the experimental IV-curve. The <em>θ</em> value is determined based on the model of the band-to-band channel as a recombination defect. With decreasing temperature, the nonradiative part of the band-to-band channel critically decreases, while the radiative part does not depend on temperature. At ultimately low temperatures, the internal quantum yield of the channel tends to unity. This property allows determining <em>θ</em> values for any temperature using the analysis of the experimental temperature dependence of the electroluminescence intensity. Determining <em>g</em> and <em>θ</em> values allows finding IQE for any temperature (including room temperature). The method has been approved for LEDs fabricated on the basis of MOVPE grown AlGaAs heterostructures with InGaAs multiple quantum wells emitting at wavelength of on 850, 910 and 940 nm. All LEDs have shown maximal IQE of about 80 %–90 %.</div></div>\",\"PeriodicalId\":16159,\"journal\":{\"name\":\"Journal of Luminescence\",\"volume\":\"288 \",\"pages\":\"Article 121573\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Luminescence\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022231325005137\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Luminescence","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022231325005137","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}
Temperature depended IV-curve method for determining LED internal quantum efficiency
A new method for determining the internal quantum efficiency (IQE) of band-to-band luminescence of a light-emitting diodes (LED) is proposed and considered. The IQE value is represented by the product of g and θ values, where g is the band-to-band recombination fraction of the total current and θ is the internal quantum yield of band-to-band recombination, i.e. the fraction of the radiative part of this channel. As shown in the paper, g value can be determined from the experimental IV-curve. The θ value is determined based on the model of the band-to-band channel as a recombination defect. With decreasing temperature, the nonradiative part of the band-to-band channel critically decreases, while the radiative part does not depend on temperature. At ultimately low temperatures, the internal quantum yield of the channel tends to unity. This property allows determining θ values for any temperature using the analysis of the experimental temperature dependence of the electroluminescence intensity. Determining g and θ values allows finding IQE for any temperature (including room temperature). The method has been approved for LEDs fabricated on the basis of MOVPE grown AlGaAs heterostructures with InGaAs multiple quantum wells emitting at wavelength of on 850, 910 and 940 nm. All LEDs have shown maximal IQE of about 80 %–90 %.
期刊介绍:
The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid.
We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.