综述了氧化锡纳米颗粒的合成方法、光降解机理及其应用

IF 3.6 3区 物理与天体物理 Q2 OPTICS
Ashish Kumar , Deepika Maan , Karishma Jain , Sushil Kumar Jain , Balram Tripathi
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引用次数: 0

摘要

由于合成染料的毒性、稳定性和抗生物降解性,纺织、印刷和相关行业的合成染料持续释放对环境和健康造成严重危害。在各种半导体基光催化剂中,氧化锡(SnO2)因其高稳定性、强氧化电位和宽带隙而成为染料降解的有前途的候选材料。本文综述了SnO2光降解染料的最新研究进展。讨论了沉淀法、水热法、溶胶-凝胶法、超声波法、球磨法和微波法等多种合成方法,重点讨论了合成路线对颗粒形貌、结晶度和光催化活性的影响。阐明了SnO2的基本光催化机理,重点阐述了电荷的产生、分离和活性氧(ROS)的形成。特别关注了sno2基复合材料的发展,如与金属、金属氧化物和碳质材料的偶联,以增强可见光响应,减少电子-空穴复合,提高降解效率。此外,综述了SnO2光催化剂在染料废水处理、传感器、太阳能电池、抗菌活性和环境修复等方面的实际应用,并概述了目前面临的挑战和未来前景。本文旨在通过对结构性能关系的批判性分析,指导下一代sno2基光催化剂的设计,以实现可持续的环境净化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A comprehensive review on synthesis methods, photodegradation mechanisms, and diverse applications of tin oxide (SnO2) nanoparticles
The persistent release of synthetic dyes from textile, printing, and related industries poses severe environmental and health hazards due to their toxicity, stability and resistance to biodegradation. Among various semiconductor-based photocatalysts, tin oxide (SnO2) has emerged as a promising candidate for dye degradation owing to high stability, strong oxidation potential and wide band gap. This review provides a comprehensive overview of recent advances in the photodegradation of dyes using SnO2. Various synthesis methods including precipitation, hydrothermal, sol-gel, ultrasonication, ball milling and microwave methods are discussed with emphasis on how synthesis routes influence particle morphology, crystallinity and photocatalytic activity. The fundamental photocatalysis mechanism of SnO2 is elucidated, highlighting charge generation, separation and reactive oxygen species (ROS) formation. Special attention is given to the development of SnO2-based composites, such as coupling with metals, metal oxides, and carbonaceous materials, which enhance visible light response, reduce electron-hole recombination and improve degradation efficiency. Furthermore, the review addresses practical applications of SnO2 photocatalysts in dye wastewater treatment, sensors, solar cells, antimicrobial activity and environmental remediation, while also outlining existing challenges and future prospects. By critically analysing the structure property performance relationships, this article aims to guide the design of next-generation SnO2-based photocatalysts for sustainable environmental cleanup.
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来源期刊
Journal of Luminescence
Journal of Luminescence 物理-光学
CiteScore
6.70
自引率
13.90%
发文量
850
审稿时长
3.8 months
期刊介绍: The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.
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