{"title":"主客体驱动的三明治状环糊精膜在废水中利尿剂的瞬时吸附","authors":"Lei Zhang, , , Junyi Zhang, , , Tian Tian*, , , Meifang Yang, , , Yu-Xin Chen, , , Qin Xu, , , Peipei Li, , , Ju Wu, , , Wenjing Zhang*, , and , Huan Pang*, ","doi":"10.1021/acsmaterialslett.5c00997","DOIUrl":null,"url":null,"abstract":"<p >The widespread presence of diuretics in wastewater, driven by their growing use in managing hypertension, heart failure, and kidney disorders as well as their chemical stability and bioactivity, poses significant environmental risks. To address these limitations, we developed a host–guest interaction-driven sandwich-like nanocomposite membrane with alternating porous and fibrous layers for rapid diuretic removal. The HPβCD composite membrane (HPβCD CM) demonstrated stable adsorption performance under acid and alkaline conditions. Within 60 s, the HPβCD CM achieved >70% removal of hydrochlorothiazide, exhibiting an adsorption rate constant 2–3 times higher than those of GAC and single-component β-cyclodextrin polymers. The maximum adsorption capacities of the membrane reached 300 mg/g for HCTZ and 200 mg/g for bendroflumethiazide and indapamide. With its outstanding adsorption performance, cost-effectiveness, and ease of regeneration, the HPβCD CM represents a promising solution for advanced water treatment applications.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 10","pages":"3504–3511"},"PeriodicalIF":8.7000,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Host–Guest-Driven Sandwich-Like Cyclodextrin Membrane for Instantaneous Diuretics Adsorption in Wastewater\",\"authors\":\"Lei Zhang, , , Junyi Zhang, , , Tian Tian*, , , Meifang Yang, , , Yu-Xin Chen, , , Qin Xu, , , Peipei Li, , , Ju Wu, , , Wenjing Zhang*, , and , Huan Pang*, \",\"doi\":\"10.1021/acsmaterialslett.5c00997\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The widespread presence of diuretics in wastewater, driven by their growing use in managing hypertension, heart failure, and kidney disorders as well as their chemical stability and bioactivity, poses significant environmental risks. To address these limitations, we developed a host–guest interaction-driven sandwich-like nanocomposite membrane with alternating porous and fibrous layers for rapid diuretic removal. The HPβCD composite membrane (HPβCD CM) demonstrated stable adsorption performance under acid and alkaline conditions. Within 60 s, the HPβCD CM achieved >70% removal of hydrochlorothiazide, exhibiting an adsorption rate constant 2–3 times higher than those of GAC and single-component β-cyclodextrin polymers. The maximum adsorption capacities of the membrane reached 300 mg/g for HCTZ and 200 mg/g for bendroflumethiazide and indapamide. With its outstanding adsorption performance, cost-effectiveness, and ease of regeneration, the HPβCD CM represents a promising solution for advanced water treatment applications.</p>\",\"PeriodicalId\":19,\"journal\":{\"name\":\"ACS Materials Letters\",\"volume\":\"7 10\",\"pages\":\"3504–3511\"},\"PeriodicalIF\":8.7000,\"publicationDate\":\"2025-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Materials Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsmaterialslett.5c00997\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Materials Letters","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsmaterialslett.5c00997","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
由于利尿剂在高血压、心力衰竭和肾脏疾病的治疗中越来越多地使用，以及它们的化学稳定性和生物活性，利尿剂在废水中广泛存在，构成了重大的环境风险。为了解决这些限制，我们开发了一种主客体相互作用驱动的三明治状纳米复合膜，具有交替的多孔层和纤维层，用于快速去除利尿剂。hpβ - cd复合膜（hpβ - cd CM）在酸碱条件下均表现出稳定的吸附性能。在60 s内，hpβ - cd CM对氢氯噻嗪的去除率达到70%，其吸附速率常数比GAC和单组分β-环糊精聚合物高2-3倍。膜对HCTZ的最大吸附量为300 mg/g，对苯并氟甲肼和吲达帕胺的最大吸附量为200 mg/g。凭借其出色的吸附性能、成本效益和易于再生，HPβCD CM代表了高级水处理应用的一个有前途的解决方案。
Host–Guest-Driven Sandwich-Like Cyclodextrin Membrane for Instantaneous Diuretics Adsorption in Wastewater
The widespread presence of diuretics in wastewater, driven by their growing use in managing hypertension, heart failure, and kidney disorders as well as their chemical stability and bioactivity, poses significant environmental risks. To address these limitations, we developed a host–guest interaction-driven sandwich-like nanocomposite membrane with alternating porous and fibrous layers for rapid diuretic removal. The HPβCD composite membrane (HPβCD CM) demonstrated stable adsorption performance under acid and alkaline conditions. Within 60 s, the HPβCD CM achieved >70% removal of hydrochlorothiazide, exhibiting an adsorption rate constant 2–3 times higher than those of GAC and single-component β-cyclodextrin polymers. The maximum adsorption capacities of the membrane reached 300 mg/g for HCTZ and 200 mg/g for bendroflumethiazide and indapamide. With its outstanding adsorption performance, cost-effectiveness, and ease of regeneration, the HPβCD CM represents a promising solution for advanced water treatment applications.
期刊介绍：
ACS Materials Letters is a journal that publishes high-quality and urgent papers at the forefront of fundamental and applied research in the field of materials science. It aims to bridge the gap between materials and other disciplines such as chemistry, engineering, and biology. The journal encourages multidisciplinary and innovative research that addresses global challenges. Papers submitted to ACS Materials Letters should clearly demonstrate the need for rapid disclosure of key results. The journal is interested in various areas including the design, synthesis, characterization, and evaluation of emerging materials, understanding the relationships between structure, property, and performance, as well as developing materials for applications in energy, environment, biomedical, electronics, and catalysis. The journal has a 2-year impact factor of 11.4 and is dedicated to publishing transformative materials research with fast processing times. The editors and staff of ACS Materials Letters actively participate in major scientific conferences and engage closely with readers and authors. The journal also maintains an active presence on social media to provide authors with greater visibility.
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