{"title":"镧系多孔有机骨架的磁调制及磁热效应。","authors":"Xueying Shao, Yue Yang, Xiaofang Dong, Shen Wang, Yulu Liang, Zhongyi Liu, Hui Min, Yu-Xia Wang, Peng Cheng","doi":"10.1039/d5cc04708k","DOIUrl":null,"url":null,"abstract":"<p><p>Lanthanide-based porous organic frameworks were synthesized <i>via</i> croconate-mediated self-assembly. The Dy framework exhibits slow magnetic relaxation through coordination modulation, whereas the Gd analogue displays significant magnetocaloric effects. This work provides a versatile platform for magnetic porous framework regulation, advancing the development of next-generation spintronic materials.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Magnetic modulation and magnetocaloric effect of lanthanide porous organic frameworks with croconic acid.\",\"authors\":\"Xueying Shao, Yue Yang, Xiaofang Dong, Shen Wang, Yulu Liang, Zhongyi Liu, Hui Min, Yu-Xia Wang, Peng Cheng\",\"doi\":\"10.1039/d5cc04708k\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Lanthanide-based porous organic frameworks were synthesized <i>via</i> croconate-mediated self-assembly. The Dy framework exhibits slow magnetic relaxation through coordination modulation, whereas the Gd analogue displays significant magnetocaloric effects. This work provides a versatile platform for magnetic porous framework regulation, advancing the development of next-generation spintronic materials.</p>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-10-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc04708k\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc04708k","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Magnetic modulation and magnetocaloric effect of lanthanide porous organic frameworks with croconic acid.
Lanthanide-based porous organic frameworks were synthesized via croconate-mediated self-assembly. The Dy framework exhibits slow magnetic relaxation through coordination modulation, whereas the Gd analogue displays significant magnetocaloric effects. This work provides a versatile platform for magnetic porous framework regulation, advancing the development of next-generation spintronic materials.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.