煤与生物质混合物粉尘爆炸特性的协同效应

IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL
Lingkai Xu , Yuchen Zhu , Zhen Wang , Dongyang Qiu , Lijuan Liu , Xianfeng Chen , Chuyuan Huang
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引用次数: 0

摘要

煤粉与生物质混合粉尘爆炸对生物质能的应用构成潜在威胁。为了研究混合粉尘的爆炸机理,本文在固定粉尘浓度条件下,通过改变两种粉尘的混合比例,系统地研究了爆炸火焰特性和爆炸参数的变化。实验测量了不同混合比下火焰传播速度、火焰温度、最大爆炸压力等关键参数。结合x射线光电子能谱(XPS)和热重质谱(TG-MS)技术,对原料的组成和热解特性进行分析,进一步了解爆炸反应机理。结果表明,煤-生物质混合粉尘在爆炸过程中表现出显著的协同效应。随着生物质掺混比的变化,爆炸强度和火焰特性表现出明显的非线性响应。随着生物质比的增加,爆炸压力和火焰温度先升高后降低,表明存在临界最爆炸性混合比。此外,对爆炸后产物的XPS分析表明,碳、氢、氧等元素的迁移和官能团重构明显。该研究为理解煤-生物质混合粉尘系统的爆炸行为和本质安全控制提供了理论依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synergistic effects in dust explosion characteristics of coal and biomass mixtures
The explosion of coal powder and biomass mixed dust poses a potential threat to the application of biomass energy. To study the explosion mechanism of mixed dust, this paper systematically investigates the changes in explosion flame characteristics and explosion parameters by varying the mixing ratio of the two types of dust under fixed dust concentration conditions. Experiments measured key parameters such as flame propagation velocity, flame temperature, and maximum explosion pressure under various mixing ratios. Combined with X-ray Photoelectron Spectroscopy(XPS) and Thermogravimetry–Mass Spectrometry(TG-MS) techniques, the composition and pyrolysis characteristics of the raw materials were analyzed to gain a deeper understanding of the explosion reaction mechanism. The results indicate that coal-biomass mixed dust exhibits significant synergistic effects during the explosion. As the biomass blending ratio changes, the explosion intensity and flame characteristics exhibit obvious nonlinear responses. Specifically, the explosion pressure and flame temperature first increase and then decrease with increasing biomass ratio, indicating the existence of a critical most explosive mixing ratio. Furthermore, XPS analysis of the post-explosion products revealed significant migration and functional group restructuring of elements such as carbon, hydrogen, and oxygen. This study provides the theoretical basis for understanding the explosion behavior and intrinsic safety control of coal-biomass mixed dust systems.
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来源期刊
Process Safety and Environmental Protection
Process Safety and Environmental Protection 环境科学-工程:化工
CiteScore
11.40
自引率
15.40%
发文量
929
审稿时长
8.0 months
期刊介绍: The Process Safety and Environmental Protection (PSEP) journal is a leading international publication that focuses on the publication of high-quality, original research papers in the field of engineering, specifically those related to the safety of industrial processes and environmental protection. The journal encourages submissions that present new developments in safety and environmental aspects, particularly those that show how research findings can be applied in process engineering design and practice. PSEP is particularly interested in research that brings fresh perspectives to established engineering principles, identifies unsolved problems, or suggests directions for future research. The journal also values contributions that push the boundaries of traditional engineering and welcomes multidisciplinary papers. PSEP's articles are abstracted and indexed by a range of databases and services, which helps to ensure that the journal's research is accessible and recognized in the academic and professional communities. These databases include ANTE, Chemical Abstracts, Chemical Hazards in Industry, Current Contents, Elsevier Engineering Information database, Pascal Francis, Web of Science, Scopus, Engineering Information Database EnCompass LIT (Elsevier), and INSPEC. This wide coverage facilitates the dissemination of the journal's content to a global audience interested in process safety and environmental engineering.
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