多金属氧酸盐与硫族金属纳米杂化物组装作为高性能超级电容器的电催化剂

IF 3.4 4区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Muhammad Khalil , Fawad Ahmad , Abdul Wahab Haroon , Mohamed A. Habib , Nosheen Farooq , Muhammad Ali Khan , Muhammad Imran Khan , Abdallah Shanableh
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引用次数: 0

摘要

电极材料的低电化学效率和低循环弹性限制了除超级电容器外电池等储能设备的使用。纳米复合材料的制备,以增加比表面积和导电性能,已经成为实现显著飙升的性能和稳定性的必要条件,这是评估电极材料的重要标准,有利于超级电容器的应用。目前的工作是利用一种简单而经济的共沉淀法合成Cu3Mo2O9/WS2纳米杂化物。利用x射线粉末衍射技术(XRD)、傅里叶变换红外光谱(FT-IR)和扫描电镜(SEM)对合成材料Cu3Mo2O9、WS2和Cu3Mo2O9/WS2纳米杂化物的几何结构、化学组成、氧化能态和形态概念进行了表征。利用x射线能谱和能量色散技术(EDX)验证了所有制备材料的元素组成。在Cu3Mo2O9纳米片中加入WS2纳米花可以增强纳米杂化物的形貌。纳米杂化材料(Cu3Mo2O9/WS2)表现出优异的稳定性(1000次循环),比电容(1380 F g−1),以及比能量(47.26 Wh Kg−1),电流密度约为2.5 a g−1,由三电极恒流充电放电(GCD)系统确定,由于其增强的形貌。此外,Cu3Mo2O9/WS2纳米杂化材料优异的电化学性能在未来具有令人兴奋的技术潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Assembling of polyoxometalates with chalcogenides metals nanohybrid as competent electrocatalyst for high performance supercapacitors
The low electrochemical efficiency and low cycle resilience of materials for electrodes limit the use of energy-storing devices like batteries in addition to super-capacitors. The Preparation of nanocomposite materials to increase specific surface area furthermore conductive properties has become essential to achieving noticeably soaring performance and stability that is vital criteria designed for evaluating the material of electrodes in favor of supercapacitor applications. The current effort synthesizes a Cu3Mo2O9/WS2 nanohybrid using a straightforward and affordable coprecipitation method. Through the use of X-ray powder-diffraction techniques (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning of electron microscopy (SEM), the geometry, chemical composition, energy state like oxidation and morphological concepts of synthesized materials Cu3Mo2O9, WS2 and Cu3Mo2O9/WS2 nanohybrid were examined. All manufactured materials' elemental composition was verified using x-ray spectroscopy with energy dispersive technology (EDX). The morphology within the nanohybrid is enhanced by the addition of WS2 nanoflowers to Cu3Mo2O9 nanosheets. The nanohybrid (Cu3Mo2O9/WS2) demonstrated exceptional stability (1000 cycles), specific capacitance (1380 F g−1), as well as specific energy (47.26 Wh Kg−1) over a current density about 2.5 A g−1, as determined by a triple electrode galvanostatic charged discharge (GCD) system, thanks to its enhanced morphology. Furthermore, the Cu3Mo2O9/WS2 nanohybrid's exceptional electrochemical properties have exciting technological potential for the future.
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来源期刊
CiteScore
3.50
自引率
7.70%
发文量
492
审稿时长
3-8 weeks
期刊介绍: The Journal of the Indian Chemical Society publishes original, fundamental, theorical, experimental research work of highest quality in all areas of chemistry, biochemistry, medicinal chemistry, electrochemistry, agrochemistry, chemical engineering and technology, food chemistry, environmental chemistry, etc.
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