H+/D+/T+-N（4S）碰撞中自旋轨道诱导电荷转移

IF 1.9 3区物理与天体物理 Q2 OPTICS

Journal of Quantitative Spectroscopy & Radiative Transfer Pub Date : 2025-10-01 DOI:10.1016/j.jqsrt.2025.109697

M. Buchowiecki , T. Jíra

{"title":"H+/D+/T+-N（4S）碰撞中自旋轨道诱导电荷转移","authors":"M. Buchowiecki , T. Jíra","doi":"10.1016/j.jqsrt.2025.109697","DOIUrl":null,"url":null,"abstract":"<div><div>The charge transfer in a nonadiabatic spin–orbit induced process N(<sup>4</sup>S) + H<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span> <span><math><mo>→</mo></math></span> N<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span>(<sup>3</sup>P) + H(<sup>2</sup>S) is investigated. The cross section and the rate constant are reported and compared with other calculations, correcting the previous values based on approximate potentials.</div><div>The calculation is extended to collisions involving deuterium and tritium, which are relevant for the transport codes (such as SOLPS-ITER) used in the modeling of fusion plasma.</div><div>The method used is a combination of the Landau–Zener theory with a novel methodology based on one-dimensional Gaussian wavepacket propagation.</div></div>","PeriodicalId":16935,"journal":{"name":"Journal of Quantitative Spectroscopy & Radiative Transfer","volume":"347 ","pages":"Article 109697"},"PeriodicalIF":1.9000,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Spin–orbit induced charge transfer in H+/D+/T+-N(4S) collisions\",\"authors\":\"M. Buchowiecki , T. Jíra\",\"doi\":\"10.1016/j.jqsrt.2025.109697\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The charge transfer in a nonadiabatic spin–orbit induced process N(<sup>4</sup>S) + H<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span> <span><math><mo>→</mo></math></span> N<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span>(<sup>3</sup>P) + H(<sup>2</sup>S) is investigated. The cross section and the rate constant are reported and compared with other calculations, correcting the previous values based on approximate potentials.</div><div>The calculation is extended to collisions involving deuterium and tritium, which are relevant for the transport codes (such as SOLPS-ITER) used in the modeling of fusion plasma.</div><div>The method used is a combination of the Landau–Zener theory with a novel methodology based on one-dimensional Gaussian wavepacket propagation.</div></div>\",\"PeriodicalId\":16935,\"journal\":{\"name\":\"Journal of Quantitative Spectroscopy & Radiative Transfer\",\"volume\":\"347 \",\"pages\":\"Article 109697\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2025-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Quantitative Spectroscopy & Radiative Transfer\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022407325003590\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Quantitative Spectroscopy & Radiative Transfer","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022407325003590","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}

引用次数: 0

摘要

研究了非绝热自旋轨道诱导过程N(4S) + H+→N+(3P) + H（2S）中的电荷转移。报告了横截面和速率常数，并与其他计算进行了比较，修正了基于近似电位的先前值。计算扩展到涉及氘和氚的碰撞，这与用于聚变等离子体建模的传输代码（如SOLPS-ITER）有关。该方法结合了朗道-齐纳理论和一种基于一维高斯波包传播的新方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Spin–orbit induced charge transfer in H+/D+/T+-N(4S) collisions

The charge transfer in a nonadiabatic spin–orbit induced process N(⁴S) + H

^{+}

\to

^{+}

(³P) + H(²S) is investigated. The cross section and the rate constant are reported and compared with other calculations, correcting the previous values based on approximate potentials.

The calculation is extended to collisions involving deuterium and tritium, which are relevant for the transport codes (such as SOLPS-ITER) used in the modeling of fusion plasma.

The method used is a combination of the Landau–Zener theory with a novel methodology based on one-dimensional Gaussian wavepacket propagation.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Quantitative Spectroscopy & Radiative Transfer 物理-光谱学

CiteScore

5.30

自引率

21.70%

发文量

273

审稿时长

58 days

期刊介绍： Papers with the following subject areas are suitable for publication in the Journal of Quantitative Spectroscopy and Radiative Transfer: - Theoretical and experimental aspects of the spectra of atoms, molecules, ions, and plasmas. - Spectral lineshape studies including models and computational algorithms. - Atmospheric spectroscopy. - Theoretical and experimental aspects of light scattering. - Application of light scattering in particle characterization and remote sensing. - Application of light scattering in biological sciences and medicine. - Radiative transfer in absorbing, emitting, and scattering media. - Radiative transfer in stochastic media.