{"title":"AgCoO2/g-C3N4纳米复合材料的开发:高性能超级电容器和光催化染料降解双功能催化剂","authors":"Orawan Rojviroon , Kumaresan Lakshmanan , Vasanthi Palanisamy , Ranjith Rajendran , Bharani Narayanan , Mangalaraja Ramalinga Viswanathan , Elavarasan Nagaraj , Thammasak Rojviroon","doi":"10.1016/j.diamond.2025.112897","DOIUrl":null,"url":null,"abstract":"<div><div>Addressing the dual challenges of sustainable energy storage and water purification, this study presents a bifunctional AgCoO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> nanocomposite engineered for high-performance electrochemical and photocatalytic applications. The composite was synthesized via a simple hydrothermal process, resulting in nanoplate-like AgCoO<sub>2</sub> uniformly anchored onto g-C<sub>3</sub>N<sub>4</sub> nanosheets. Notably, the incorporation of g-C<sub>3</sub>N<sub>4</sub> enhances the overall amorphous nature of the composite, which plays a critical role in boosting both charge storage and photocatalytic activity. Comparative studies with pure AgCoO<sub>2</sub> and g-C<sub>3</sub>N<sub>4</sub> confirm the superior performance of the hybrid material. Electrochemical analysis revealed excellent pseudocapacitive behavior, delivering a high specific capacitance of 867.5 F/g at 1 A/g and outstanding cycling stability with 90 % capacitance retention after 12,000 cycles. Simultaneously, the composite exhibited enhanced photocatalytic efficiency, degrading 92 % of methylene blue under visible light within 120 min. The synergistic integration of AgCoO<sub>2</sub> with amorphous-rich g-C<sub>3</sub>N<sub>4</sub> improves charge separation, light absorption, and surface reactivity, enabling effective dual-functionality. These findings highlight AgCoO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> as a promising candidate for next-generation supercapacitor devices and advanced wastewater treatment technologies.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"159 ","pages":"Article 112897"},"PeriodicalIF":5.1000,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of AgCoO2/g-C3N4 nanocomposite: A robust catalyst for dual-functionality in high-performance supercapacitors and photocatalytic dye degradation\",\"authors\":\"Orawan Rojviroon , Kumaresan Lakshmanan , Vasanthi Palanisamy , Ranjith Rajendran , Bharani Narayanan , Mangalaraja Ramalinga Viswanathan , Elavarasan Nagaraj , Thammasak Rojviroon\",\"doi\":\"10.1016/j.diamond.2025.112897\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Addressing the dual challenges of sustainable energy storage and water purification, this study presents a bifunctional AgCoO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> nanocomposite engineered for high-performance electrochemical and photocatalytic applications. 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引用次数: 0
摘要
为了解决可持续能源储存和水净化的双重挑战,本研究提出了一种双功能AgCoO2/g-C3N4纳米复合材料,用于高性能电化学和光催化应用。该复合材料通过简单的水热法合成,得到了纳米板状AgCoO2均匀锚定在g-C3N4纳米片上。值得注意的是,g-C3N4的加入增强了复合材料的整体无定形性质,这在提高电荷存储和光催化活性方面起着关键作用。与纯AgCoO2和g-C3N4的对比研究证实了该杂化材料的优越性能。电化学分析显示了优异的赝电容行为,在1 a /g下提供867.5 F/g的高比电容,并且在12,000次循环后具有优异的循环稳定性,电容保持率为90%。同时,该复合材料表现出增强的光催化效率,在可见光下120 min内可降解92%的亚甲基蓝。AgCoO2与富非晶g-C3N4的协同集成改善了电荷分离、光吸收和表面反应性,实现了有效的双功能。这些发现突出了AgCoO2/g-C3N4作为下一代超级电容器器件和先进废水处理技术的有前途的候选者。
Development of AgCoO2/g-C3N4 nanocomposite: A robust catalyst for dual-functionality in high-performance supercapacitors and photocatalytic dye degradation
Addressing the dual challenges of sustainable energy storage and water purification, this study presents a bifunctional AgCoO2/g-C3N4 nanocomposite engineered for high-performance electrochemical and photocatalytic applications. The composite was synthesized via a simple hydrothermal process, resulting in nanoplate-like AgCoO2 uniformly anchored onto g-C3N4 nanosheets. Notably, the incorporation of g-C3N4 enhances the overall amorphous nature of the composite, which plays a critical role in boosting both charge storage and photocatalytic activity. Comparative studies with pure AgCoO2 and g-C3N4 confirm the superior performance of the hybrid material. Electrochemical analysis revealed excellent pseudocapacitive behavior, delivering a high specific capacitance of 867.5 F/g at 1 A/g and outstanding cycling stability with 90 % capacitance retention after 12,000 cycles. Simultaneously, the composite exhibited enhanced photocatalytic efficiency, degrading 92 % of methylene blue under visible light within 120 min. The synergistic integration of AgCoO2 with amorphous-rich g-C3N4 improves charge separation, light absorption, and surface reactivity, enabling effective dual-functionality. These findings highlight AgCoO2/g-C3N4 as a promising candidate for next-generation supercapacitor devices and advanced wastewater treatment technologies.
期刊介绍:
DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices.
The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.