{"title":"通过位置选择性C-H溴化直接光化学交叉酯化醇","authors":"Atsuya Miyamoto, Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka","doi":"10.1039/d5cc03371c","DOIUrl":null,"url":null,"abstract":"We have developed a direct photochemical cross-esterification of alcohols that proceeds via the in-situ generation of acyl bromides. The C-H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"42 1","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Direct Photochemical Cross-Esterification of Alcohols via Site-Selective C-H Bromination\",\"authors\":\"Atsuya Miyamoto, Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka\",\"doi\":\"10.1039/d5cc03371c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We have developed a direct photochemical cross-esterification of alcohols that proceeds via the in-situ generation of acyl bromides. The C-H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"42 1\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc03371c\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc03371c","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
The Direct Photochemical Cross-Esterification of Alcohols via Site-Selective C-H Bromination
We have developed a direct photochemical cross-esterification of alcohols that proceeds via the in-situ generation of acyl bromides. The C-H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.