{"title":"烟气冷凝模拟剂中碘离子阴离子的直接电化学分析","authors":"Junhua Jiang, Kathryn Taylor-Pashow, Corey Martin","doi":"10.1007/s10967-025-10337-2","DOIUrl":null,"url":null,"abstract":"<div><p>Direct electrochemical analysis of iodide anions in a Hanford off-gas condensate simulant has been studied by the cyclic voltammetry and chronoamperometry method. Well-developed cyclic voltammograms displaying distinguishable oxidation and reduction peaks have been obtained on gold and glassy carbon disc electrodes. The chronoamperograms are characteristic of fast current decays at short times and slow current decays at longer times. Both the cyclic voltammograms and the chronoamperograms are strongly dependent upon the concentration of iodide ions. Moreover, the voltametric peak currents and the sampled slow-decay currents exhibit good linear relationship with the concentrations. The lower detection limit of approximately 0.9 ppm iodide has been obtained on the gold electrode from the cyclic voltametric measurements. These results suggest that it is prospective to develop the electroanalytical method to measure the concentration of iodide ions in a complicated environment such as contaminated underground water and radioactive liquid wastes.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 9","pages":"5951 - 5957"},"PeriodicalIF":1.6000,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Direct electrochemical analysis of iodide anions in an off-gas condensate simulant\",\"authors\":\"Junhua Jiang, Kathryn Taylor-Pashow, Corey Martin\",\"doi\":\"10.1007/s10967-025-10337-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Direct electrochemical analysis of iodide anions in a Hanford off-gas condensate simulant has been studied by the cyclic voltammetry and chronoamperometry method. Well-developed cyclic voltammograms displaying distinguishable oxidation and reduction peaks have been obtained on gold and glassy carbon disc electrodes. The chronoamperograms are characteristic of fast current decays at short times and slow current decays at longer times. Both the cyclic voltammograms and the chronoamperograms are strongly dependent upon the concentration of iodide ions. Moreover, the voltametric peak currents and the sampled slow-decay currents exhibit good linear relationship with the concentrations. The lower detection limit of approximately 0.9 ppm iodide has been obtained on the gold electrode from the cyclic voltametric measurements. These results suggest that it is prospective to develop the electroanalytical method to measure the concentration of iodide ions in a complicated environment such as contaminated underground water and radioactive liquid wastes.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":661,\"journal\":{\"name\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"volume\":\"334 9\",\"pages\":\"5951 - 5957\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2025-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10967-025-10337-2\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-025-10337-2","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Direct electrochemical analysis of iodide anions in an off-gas condensate simulant
Direct electrochemical analysis of iodide anions in a Hanford off-gas condensate simulant has been studied by the cyclic voltammetry and chronoamperometry method. Well-developed cyclic voltammograms displaying distinguishable oxidation and reduction peaks have been obtained on gold and glassy carbon disc electrodes. The chronoamperograms are characteristic of fast current decays at short times and slow current decays at longer times. Both the cyclic voltammograms and the chronoamperograms are strongly dependent upon the concentration of iodide ions. Moreover, the voltametric peak currents and the sampled slow-decay currents exhibit good linear relationship with the concentrations. The lower detection limit of approximately 0.9 ppm iodide has been obtained on the gold electrode from the cyclic voltametric measurements. These results suggest that it is prospective to develop the electroanalytical method to measure the concentration of iodide ions in a complicated environment such as contaminated underground water and radioactive liquid wastes.
期刊介绍：
An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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