{"title":"具有准类型-Ι带对准的石墨烯/PbTe/n-Si异质结光电探测器实现宽带和偏置可调光响应。","authors":"Lixin Liu,Jiayue Han,Jun Gou,Guangxu Mao,Hang Yu,Han Dou,Yunlu Lian,Jinling Xie,Jiamin Jiang,Baohua An,Lei Guo,Hongxi Zhou,Chao Chen,Yadong Jiang,He Yu,Jun Wang","doi":"10.1021/acsami.5c15473","DOIUrl":null,"url":null,"abstract":"High-performance broadband photodetectors traditionally based on III-V and II-VI semiconductors, despite their commercial success in the near- and mid-infrared regions, suffer from high fabrication cost, poor CMOS compatibility, and the need for cryogenic cooling, thus limiting their large-scale integration. Here, we demonstrate a virtual graphene/PbTe/Si heterojunction photodetector fabricated by magnetron sputtering, offering a scalable and cost-effective route to high-performance optoelectronic devices. The device exhibits a bias-tunable photoresponse governed by quantum tunneling at the PbTe/Si interface. At ±3 V biases, the photocurrent differs by nearly 2 orders of magnitude under low light intensities, whereas a symmetric response with less than 5% variation is observed at high light intensities. Exploiting this nonlinear response, we establish a dual-mode optical communication scheme, where plaintext is transmitted at high intensities and encrypted inverse codes are generated under low intensities. This built-in encoding functionality enables a simple yet effective strategy for secure optical communication without complex external circuits. Moreover, the CMOS-compatible fabrication process ensures seamless integration with existing silicon photonic platforms, highlighting the potential of this approach for future large-scale on-chip optical communication technologies.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"10 1","pages":""},"PeriodicalIF":8.2000,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Graphene/PbTe/n-Si Heterojunction Photodetector with Quasi-Type-Ι Band Alignment Enables a Broadband and Bias-Tunable Photoresponse.\",\"authors\":\"Lixin Liu,Jiayue Han,Jun Gou,Guangxu Mao,Hang Yu,Han Dou,Yunlu Lian,Jinling Xie,Jiamin Jiang,Baohua An,Lei Guo,Hongxi Zhou,Chao Chen,Yadong Jiang,He Yu,Jun Wang\",\"doi\":\"10.1021/acsami.5c15473\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"High-performance broadband photodetectors traditionally based on III-V and II-VI semiconductors, despite their commercial success in the near- and mid-infrared regions, suffer from high fabrication cost, poor CMOS compatibility, and the need for cryogenic cooling, thus limiting their large-scale integration. Here, we demonstrate a virtual graphene/PbTe/Si heterojunction photodetector fabricated by magnetron sputtering, offering a scalable and cost-effective route to high-performance optoelectronic devices. The device exhibits a bias-tunable photoresponse governed by quantum tunneling at the PbTe/Si interface. At ±3 V biases, the photocurrent differs by nearly 2 orders of magnitude under low light intensities, whereas a symmetric response with less than 5% variation is observed at high light intensities. Exploiting this nonlinear response, we establish a dual-mode optical communication scheme, where plaintext is transmitted at high intensities and encrypted inverse codes are generated under low intensities. This built-in encoding functionality enables a simple yet effective strategy for secure optical communication without complex external circuits. Moreover, the CMOS-compatible fabrication process ensures seamless integration with existing silicon photonic platforms, highlighting the potential of this approach for future large-scale on-chip optical communication technologies.\",\"PeriodicalId\":5,\"journal\":{\"name\":\"ACS Applied Materials & Interfaces\",\"volume\":\"10 1\",\"pages\":\"\"},\"PeriodicalIF\":8.2000,\"publicationDate\":\"2025-10-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Materials & Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acsami.5c15473\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Materials & Interfaces","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsami.5c15473","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Graphene/PbTe/n-Si Heterojunction Photodetector with Quasi-Type-Ι Band Alignment Enables a Broadband and Bias-Tunable Photoresponse.
High-performance broadband photodetectors traditionally based on III-V and II-VI semiconductors, despite their commercial success in the near- and mid-infrared regions, suffer from high fabrication cost, poor CMOS compatibility, and the need for cryogenic cooling, thus limiting their large-scale integration. Here, we demonstrate a virtual graphene/PbTe/Si heterojunction photodetector fabricated by magnetron sputtering, offering a scalable and cost-effective route to high-performance optoelectronic devices. The device exhibits a bias-tunable photoresponse governed by quantum tunneling at the PbTe/Si interface. At ±3 V biases, the photocurrent differs by nearly 2 orders of magnitude under low light intensities, whereas a symmetric response with less than 5% variation is observed at high light intensities. Exploiting this nonlinear response, we establish a dual-mode optical communication scheme, where plaintext is transmitted at high intensities and encrypted inverse codes are generated under low intensities. This built-in encoding functionality enables a simple yet effective strategy for secure optical communication without complex external circuits. Moreover, the CMOS-compatible fabrication process ensures seamless integration with existing silicon photonic platforms, highlighting the potential of this approach for future large-scale on-chip optical communication technologies.
期刊介绍:
ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.