{"title":"基于h-BN/MoTe2/BP异质结构的w型反双极晶体管。","authors":"Enxiu Wu*, , , Yuexuan Ma, , , Qijia Tian, , , Zhiyuan Wang, , , Zhaoqi Song, , , Shida Huo, , , Fanying Meng, , , Yuan Xie, , and , Caofeng Pan, ","doi":"10.1021/acsnano.5c11809","DOIUrl":null,"url":null,"abstract":"<p >The development of multifunctional device architectures capable of integrating logic, analog, and optoelectronic functions is critical for overcoming the scaling and energy efficiency limitations of conventional CMOS technologies. Antiambipolar transistors (AATs), with their nonmonotonic transfer characteristics and central Λ-shaped region, provide an attractive platform for implementing multivalued logic operations, compact frequency multipliers, and photodetectors. Here, we present a high-performance W-shaped AAT based on an h-BN/MoTe<sub>2</sub>/BP van der Waals heterostructure. The device exhibits four discrete conductance states and a symmetric Λ-region centered at <i>V</i><sub>gs</sub> = 0 V, with a high on/off current ratio exceeding 10<sup>5</sup> and peak currents in the microampere range. These properties enable the implementation of a ternary inverter with uniformly spaced 20 V logic windows and excellent operational stability over 200 switching cycles. In addition, the symmetric Λ-region facilitates bias-free frequency doubling, providing a low-power solution for analog signal processing. Furthermore, the device functions as a gate-tunable photovoltaic photodetector with dynamically reversible photocurrent polarity. It achieves a rectification ratio ranging from 10<sup>–3</sup> to 10<sup>3</sup>, a dark current below 0.5 pA, a photoresponsivity of 0.29 A/W, an external quantum efficiency (EQE) of 69.4%, and a fast response time of 100 μs. These results position W-shaped AATs as a potential platform for next-generation nanoelectronic and optoelectronic systems requiring reconfigurability, energy efficiency, and high integration density.</p>","PeriodicalId":21,"journal":{"name":"ACS Nano","volume":"19 40","pages":"35701–35711"},"PeriodicalIF":16.0000,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"W-Shaped Antiambipolar Transistors Based on h-BN/MoTe2/BP Heterostructures\",\"authors\":\"Enxiu Wu*, , , Yuexuan Ma, , , Qijia Tian, , , Zhiyuan Wang, , , Zhaoqi Song, , , Shida Huo, , , Fanying Meng, , , Yuan Xie, , and , Caofeng Pan, \",\"doi\":\"10.1021/acsnano.5c11809\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The development of multifunctional device architectures capable of integrating logic, analog, and optoelectronic functions is critical for overcoming the scaling and energy efficiency limitations of conventional CMOS technologies. Antiambipolar transistors (AATs), with their nonmonotonic transfer characteristics and central Λ-shaped region, provide an attractive platform for implementing multivalued logic operations, compact frequency multipliers, and photodetectors. Here, we present a high-performance W-shaped AAT based on an h-BN/MoTe<sub>2</sub>/BP van der Waals heterostructure. The device exhibits four discrete conductance states and a symmetric Λ-region centered at <i>V</i><sub>gs</sub> = 0 V, with a high on/off current ratio exceeding 10<sup>5</sup> and peak currents in the microampere range. These properties enable the implementation of a ternary inverter with uniformly spaced 20 V logic windows and excellent operational stability over 200 switching cycles. In addition, the symmetric Λ-region facilitates bias-free frequency doubling, providing a low-power solution for analog signal processing. Furthermore, the device functions as a gate-tunable photovoltaic photodetector with dynamically reversible photocurrent polarity. It achieves a rectification ratio ranging from 10<sup>–3</sup> to 10<sup>3</sup>, a dark current below 0.5 pA, a photoresponsivity of 0.29 A/W, an external quantum efficiency (EQE) of 69.4%, and a fast response time of 100 μs. These results position W-shaped AATs as a potential platform for next-generation nanoelectronic and optoelectronic systems requiring reconfigurability, energy efficiency, and high integration density.</p>\",\"PeriodicalId\":21,\"journal\":{\"name\":\"ACS Nano\",\"volume\":\"19 40\",\"pages\":\"35701–35711\"},\"PeriodicalIF\":16.0000,\"publicationDate\":\"2025-10-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Nano\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsnano.5c11809\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Nano","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsnano.5c11809","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
能够集成逻辑、模拟和光电子功能的多功能器件架构的发展对于克服传统CMOS技术的缩放和能效限制至关重要。反双极性晶体管(AATs)具有非单调传输特性和中心Λ-shaped区域,为实现多值逻辑运算、紧凑的频率乘法器和光电探测器提供了一个有吸引力的平台。在这里,我们提出了一种基于h-BN/MoTe2/BP范德华异质结构的高性能w形AAT。该器件具有四个离散的电导状态和一个以Vgs = 0 V为中心的对称Λ-region,具有超过105的高通/关电流比和在微安范围内的峰值电流。这些特性能够实现具有均匀间隔20v逻辑窗口的三元逆变器,并且在200个开关周期内具有出色的运行稳定性。此外,对称的Λ-region有助于无偏置倍频,为模拟信号处理提供低功耗解决方案。此外,该器件还可作为具有动态可逆光电流极性的栅极可调谐光伏光电探测器。该器件的整流比范围为10-3 ~ 103,暗电流小于0.5 pA,光响应率为0.29 a /W,外量子效率(EQE)为69.4%,响应时间为100 μs。这些结果将w形aat定位为下一代纳米电子和光电子系统的潜在平台,这些系统需要可重构性、能效和高集成度。
W-Shaped Antiambipolar Transistors Based on h-BN/MoTe2/BP Heterostructures
The development of multifunctional device architectures capable of integrating logic, analog, and optoelectronic functions is critical for overcoming the scaling and energy efficiency limitations of conventional CMOS technologies. Antiambipolar transistors (AATs), with their nonmonotonic transfer characteristics and central Λ-shaped region, provide an attractive platform for implementing multivalued logic operations, compact frequency multipliers, and photodetectors. Here, we present a high-performance W-shaped AAT based on an h-BN/MoTe2/BP van der Waals heterostructure. The device exhibits four discrete conductance states and a symmetric Λ-region centered at Vgs = 0 V, with a high on/off current ratio exceeding 105 and peak currents in the microampere range. These properties enable the implementation of a ternary inverter with uniformly spaced 20 V logic windows and excellent operational stability over 200 switching cycles. In addition, the symmetric Λ-region facilitates bias-free frequency doubling, providing a low-power solution for analog signal processing. Furthermore, the device functions as a gate-tunable photovoltaic photodetector with dynamically reversible photocurrent polarity. It achieves a rectification ratio ranging from 10–3 to 103, a dark current below 0.5 pA, a photoresponsivity of 0.29 A/W, an external quantum efficiency (EQE) of 69.4%, and a fast response time of 100 μs. These results position W-shaped AATs as a potential platform for next-generation nanoelectronic and optoelectronic systems requiring reconfigurability, energy efficiency, and high integration density.
期刊介绍:
ACS Nano, published monthly, serves as an international forum for comprehensive articles on nanoscience and nanotechnology research at the intersections of chemistry, biology, materials science, physics, and engineering. The journal fosters communication among scientists in these communities, facilitating collaboration, new research opportunities, and advancements through discoveries. ACS Nano covers synthesis, assembly, characterization, theory, and simulation of nanostructures, nanobiotechnology, nanofabrication, methods and tools for nanoscience and nanotechnology, and self- and directed-assembly. Alongside original research articles, it offers thorough reviews, perspectives on cutting-edge research, and discussions envisioning the future of nanoscience and nanotechnology.