Wenting Kong*, , , Hao Jia, , , Yan Zhao, , and , Wen Xu,
{"title":"耐久的超疏水涂层,具有可调的超润湿性,用于油水分离","authors":"Wenting Kong*, , , Hao Jia, , , Yan Zhao, , and , Wen Xu, ","doi":"10.1021/acsanm.5c03198","DOIUrl":null,"url":null,"abstract":"<p >Smart membranes with adjustable superwettability are promising candidates for addressing complex challenges, such as treating oily domestic wastewater and industrial oil leakages. In this study, a durable superhydrophobic coating with switchable wettability was fabricated on a cotton fabric. The coated fabric exhibited a rapid transition to a superhydrophilic/underwater superoleophobic state via a “wetting-displacing” process, and can recover its original superhydrophobicity upon drying. The underwater–oil contact angle was further modulated by adjusting the ratio of the chemical components to the coating thickness. Inspired by the wettability pattern of the Stenocara beetle, an underwater superoleophobic/philic patterned fabric for efficient oi–water separation was developed. The influence of the wettability pattern geometry on the separation efficiency and flux was also investigated. The coated fabric was used to separate multiple types of oil/water mixtures with a separation efficiency of over 99%.</p>","PeriodicalId":6,"journal":{"name":"ACS Applied Nano Materials","volume":"8 39","pages":"18817–18828"},"PeriodicalIF":5.5000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Durable Superhydrophobic Coating with Adjustable Superwettability for Oil–Water Separation\",\"authors\":\"Wenting Kong*, , , Hao Jia, , , Yan Zhao, , and , Wen Xu, \",\"doi\":\"10.1021/acsanm.5c03198\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Smart membranes with adjustable superwettability are promising candidates for addressing complex challenges, such as treating oily domestic wastewater and industrial oil leakages. In this study, a durable superhydrophobic coating with switchable wettability was fabricated on a cotton fabric. The coated fabric exhibited a rapid transition to a superhydrophilic/underwater superoleophobic state via a “wetting-displacing” process, and can recover its original superhydrophobicity upon drying. The underwater–oil contact angle was further modulated by adjusting the ratio of the chemical components to the coating thickness. Inspired by the wettability pattern of the Stenocara beetle, an underwater superoleophobic/philic patterned fabric for efficient oi–water separation was developed. The influence of the wettability pattern geometry on the separation efficiency and flux was also investigated. The coated fabric was used to separate multiple types of oil/water mixtures with a separation efficiency of over 99%.</p>\",\"PeriodicalId\":6,\"journal\":{\"name\":\"ACS Applied Nano Materials\",\"volume\":\"8 39\",\"pages\":\"18817–18828\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2025-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Nano Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsanm.5c03198\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Nano Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsanm.5c03198","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Durable Superhydrophobic Coating with Adjustable Superwettability for Oil–Water Separation
Smart membranes with adjustable superwettability are promising candidates for addressing complex challenges, such as treating oily domestic wastewater and industrial oil leakages. In this study, a durable superhydrophobic coating with switchable wettability was fabricated on a cotton fabric. The coated fabric exhibited a rapid transition to a superhydrophilic/underwater superoleophobic state via a “wetting-displacing” process, and can recover its original superhydrophobicity upon drying. The underwater–oil contact angle was further modulated by adjusting the ratio of the chemical components to the coating thickness. Inspired by the wettability pattern of the Stenocara beetle, an underwater superoleophobic/philic patterned fabric for efficient oi–water separation was developed. The influence of the wettability pattern geometry on the separation efficiency and flux was also investigated. The coated fabric was used to separate multiple types of oil/water mixtures with a separation efficiency of over 99%.
期刊介绍:
ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.