WC加入对ZrB2/ sic基uhtcmc力学性能和抗氧化性能的影响

IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Antonio Vinci, Matteo Mor, Luca Zoli, Diletta Sciti
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引用次数: 0

摘要

研究了碳纤维增强ZrB2/SiC/WC复合材料的烧结性能、力学性能和抗氧化性能。烧结温度为1800 ~ 2000℃,热压温度为40 MPa。WC在此过程中被完全消耗,形成的微观组织为Zr1−xWxC固溶体和ZrB2晶界处的WB。在1800℃下烧结的试样孔隙率高,而在2000℃下烧结的试样致密,但纤维降解严重。在保持纤维完整性的同时,在1900°C的温度下可以获得92%的相对密度,这反映在更高的机械性能上。将这些结果与参考材料ZrB2/SiC复合材料进行比较,WC的加入似乎对力学性能没有明显影响,但它促进了氧化过程中更致密的氧化层的形成,从而使材料在1650℃的空气中具有更高的保护性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of WC addition on the mechanical properties and oxidation resistance of ZrB2/SiC-based UHTCMCs

Effect of WC addition on the mechanical properties and oxidation resistance of ZrB2/SiC-based UHTCMCs

The sintering behavior, mechanical properties, and oxidation resistance of carbon fiber reinforced ZrB2/SiC/WC composites were investigated. Sintering was carried out between 1800 and 2000°C via hot pressing at 40 MPa. WC was completely consumed in the process, and the resulting microstructure was characterized by the formation of Zr1−xWxC solid solutions and WB at the ZrB2 border grains. The sample sintered at 1800°C was characterized by high porosity, whereas the sample sintered at 2000°C was fully dense, but fibers were severely degraded. A temperature of 1900°C allowed to obtain 92% relative density while preserving the fibers integrity, which was reflected in the higher mechanical properties. Comparing these results with a reference ZrB2/SiC composite, the addition of WC did not seem to significantly affect the mechanical properties, but it promoted the formation of a more compact oxide scale during oxidation, resulting in the higher protection of the material at 1650°C in air.

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来源期刊
International Journal of Applied Ceramic Technology
International Journal of Applied Ceramic Technology 工程技术-材料科学:硅酸盐
CiteScore
3.90
自引率
9.50%
发文量
280
审稿时长
4.5 months
期刊介绍: The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas: Nanotechnology applications; Ceramic Armor; Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors); Ceramic Matrix Composites; Functional Materials; Thermal and Environmental Barrier Coatings; Bioceramic Applications; Green Manufacturing; Ceramic Processing; Glass Technology; Fiber optics; Ceramics in Environmental Applications; Ceramics in Electronic, Photonic and Magnetic Applications;
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