覆盖特性：耐用的非均相Pd-PNP螯合物，用于碳的形成在连续流系统（ChemSusChem 19/2025）

IF 6.6 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

ChemSusChem Pub Date : 2025-10-01 DOI:10.1002/cssc.70167

Naoya Sakurada, Kanon Kawai, Yuka Abe, Kwihwan Kobayashi, Shinya Mine, Noriko Miyamoto, Tsuyoshi Yamada, Takashi Ikawa, Hironao Sajiki

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引用次数: 0

摘要

封面特征显示，在一个让人联想到肿胀的梅里菲尔德树脂的聚合物孔内，一条连续的溪流穿过pnp钳位的景观，这些钳位固定了钯。在流动条件下进行稳健的Mizoroki-Heck转化过程中，催化剂被限制在树脂微环境中，以抑制浸出并维持长时间的操作。隧道般的视角传达了通过固定床的物质运输，而整体轮廓巧妙地暗示了“SCORPI”，唤起了蝎子的形式。更多信息可以在T. Ikawa及其同事的研究文章中找到（DOI: 10.1002/cssc.202501205）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Durable Heterogeneous Pd-PNP Pincer Complex for CarbonCarbon Bond Formation in Continuous-Flow Systems (ChemSusChem 19/2025)

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Cover Feature: Durable Heterogeneous Pd-PNP Pincer Complex for CarbonCarbon Bond Formation in Continuous-Flow Systems (ChemSusChem 19/2025)

The Cover Feature shows how, within a polymer pore reminiscent of swollen Merrifield resin, a continuous stream traverses a landscape of PNP-pincer sites that immobilize palladium species. During a robust Mizoroki–Heck transformation under flow conditions, the catalyst is confined to the resin microenvironment to suppress leaching and sustain extended operation. The tunnel-like perspective conveys mass transport through the fixed bed, while the overall silhouette subtly alludes to “SCORPI”, evoking the form of a scorpion. More information can be found in the Research Article by T. Ikawa and co-workers (DOI: 10.1002/cssc.202501205).

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来源期刊

ChemSusChem 化学-化学综合

CiteScore

15.80

自引率

4.80%

发文量

555

审稿时长

1.8 months

期刊介绍： ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology