Loukia-Pantzechroula Merkouri, Maila Danielis, Andrea Braga, Tomas Ramirez Reina, Alessandro Trovarelli, Sara Colussi and Melis S. Duyar
{"title":"机械化学合成双功能材料甲烷碳捕集与干重整的综合研究","authors":"Loukia-Pantzechroula Merkouri, Maila Danielis, Andrea Braga, Tomas Ramirez Reina, Alessandro Trovarelli, Sara Colussi and Melis S. Duyar","doi":"10.1039/D5SU00317B","DOIUrl":null,"url":null,"abstract":"<p >Herein we report a green mechanochemical synthesis with low energy input of dual-function materials for integrated CO<small><sub>2</sub></small> capture and dry reforming of methane. The materials produced syngas during the CH<small><sub>4</sub></small> step (up to 0.6 mmol g<small><sup>−1</sup></small> CO and 7.7 mmol g<small><sup>−1</sup></small> H<small><sub>2</sub></small>) and CO during the CO<small><sub>2</sub></small> step (up to 3.1 mmol g<small><sup>−1</sup></small>) <em>via</em> the reverse Boudouard reaction due to the carbon produced from CH<small><sub>4</sub></small> cracking.</p>","PeriodicalId":74745,"journal":{"name":"RSC sustainability","volume":" 10","pages":" 4457-4465"},"PeriodicalIF":4.9000,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/su/d5su00317b?page=search","citationCount":"0","resultStr":"{\"title\":\"Integrated carbon capture and dry reforming of methane of mechanochemically synthesised dual-function materials\",\"authors\":\"Loukia-Pantzechroula Merkouri, Maila Danielis, Andrea Braga, Tomas Ramirez Reina, Alessandro Trovarelli, Sara Colussi and Melis S. Duyar\",\"doi\":\"10.1039/D5SU00317B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Herein we report a green mechanochemical synthesis with low energy input of dual-function materials for integrated CO<small><sub>2</sub></small> capture and dry reforming of methane. The materials produced syngas during the CH<small><sub>4</sub></small> step (up to 0.6 mmol g<small><sup>−1</sup></small> CO and 7.7 mmol g<small><sup>−1</sup></small> H<small><sub>2</sub></small>) and CO during the CO<small><sub>2</sub></small> step (up to 3.1 mmol g<small><sup>−1</sup></small>) <em>via</em> the reverse Boudouard reaction due to the carbon produced from CH<small><sub>4</sub></small> cracking.</p>\",\"PeriodicalId\":74745,\"journal\":{\"name\":\"RSC sustainability\",\"volume\":\" 10\",\"pages\":\" 4457-4465\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2025-08-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/su/d5su00317b?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"RSC sustainability\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/su/d5su00317b\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC sustainability","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/su/d5su00317b","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Integrated carbon capture and dry reforming of methane of mechanochemically synthesised dual-function materials
Herein we report a green mechanochemical synthesis with low energy input of dual-function materials for integrated CO2 capture and dry reforming of methane. The materials produced syngas during the CH4 step (up to 0.6 mmol g−1 CO and 7.7 mmol g−1 H2) and CO during the CO2 step (up to 3.1 mmol g−1) via the reverse Boudouard reaction due to the carbon produced from CH4 cracking.