Ramakrishnan S. , Rajeshkannan Sundararajan , V. Ramya , M. Elangovan
{"title":"用Gegenbauer图神经网络方法提高氢氧化钠地聚合物混凝土强度","authors":"Ramakrishnan S. , Rajeshkannan Sundararajan , V. Ramya , M. Elangovan","doi":"10.1080/1023666X.2025.2490782","DOIUrl":null,"url":null,"abstract":"<div><div>An eco-friendly and inventive alternative to cement-based concrete is geopolymer concrete (GPC) due to its reduced carbon footprint, as it completely replaces cement. Despite their environmental benefits, the mechanical performance of GPC is highly sensitive to the mix of proportions and curing conditions, presenting significant challenges in achieving consistent strength. To enhance the strength and mechanical properties of GPC with sodium hydroxide (NaOH), a unique approach using Gegenbauer graph neural networks (GGNN) is presented in this work. The main objectives of this study include reducing CO<sub>2</sub> emissions. The strength of GPC with NaOH is predicted using GGNN. The GGNN method is also used to analyze the mechanical properties of GPC under different NaOH molarities and different ratios of sodium silicate to NaOH. The proposed method is simulated in MATLAB and is compared with existing methods like long short-term memory (LSTM), artificial neural network (ANN), and back propagation neural network (BPNN). It is found that the oven-cured GPC achieved better mechanical strength compared to the ambient-cured GPC. The proposed model attained the highest compressive strength (CS) of 75.42 MPa along with a high correlation coefficient of 0.9871 compared to the previous studies. In contrast to the existing methods, the proposed model achieved a high prediction accuracy of 98.5% along with a low CO<sub>2</sub> emission of 7% demonstrating its superior performance in accurately predicting the mechanical strength and reducing carbon footprints. This indicates the robustness and reliability of the proposed model for optimizing material properties and advancing the field of sustainable construction materials.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"30 7","pages":"Pages 761-776"},"PeriodicalIF":1.6000,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhancing geopolymer concrete strength with sodium hydroxide using Gegenbauer graph neural networks approach\",\"authors\":\"Ramakrishnan S. , Rajeshkannan Sundararajan , V. Ramya , M. Elangovan\",\"doi\":\"10.1080/1023666X.2025.2490782\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>An eco-friendly and inventive alternative to cement-based concrete is geopolymer concrete (GPC) due to its reduced carbon footprint, as it completely replaces cement. Despite their environmental benefits, the mechanical performance of GPC is highly sensitive to the mix of proportions and curing conditions, presenting significant challenges in achieving consistent strength. To enhance the strength and mechanical properties of GPC with sodium hydroxide (NaOH), a unique approach using Gegenbauer graph neural networks (GGNN) is presented in this work. The main objectives of this study include reducing CO<sub>2</sub> emissions. The strength of GPC with NaOH is predicted using GGNN. The GGNN method is also used to analyze the mechanical properties of GPC under different NaOH molarities and different ratios of sodium silicate to NaOH. The proposed method is simulated in MATLAB and is compared with existing methods like long short-term memory (LSTM), artificial neural network (ANN), and back propagation neural network (BPNN). It is found that the oven-cured GPC achieved better mechanical strength compared to the ambient-cured GPC. The proposed model attained the highest compressive strength (CS) of 75.42 MPa along with a high correlation coefficient of 0.9871 compared to the previous studies. In contrast to the existing methods, the proposed model achieved a high prediction accuracy of 98.5% along with a low CO<sub>2</sub> emission of 7% demonstrating its superior performance in accurately predicting the mechanical strength and reducing carbon footprints. This indicates the robustness and reliability of the proposed model for optimizing material properties and advancing the field of sustainable construction materials.</div></div>\",\"PeriodicalId\":14236,\"journal\":{\"name\":\"International Journal of Polymer Analysis and Characterization\",\"volume\":\"30 7\",\"pages\":\"Pages 761-776\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2025-10-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Polymer Analysis and Characterization\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1023666X25000526\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Polymer Analysis and Characterization","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1023666X25000526","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Enhancing geopolymer concrete strength with sodium hydroxide using Gegenbauer graph neural networks approach
An eco-friendly and inventive alternative to cement-based concrete is geopolymer concrete (GPC) due to its reduced carbon footprint, as it completely replaces cement. Despite their environmental benefits, the mechanical performance of GPC is highly sensitive to the mix of proportions and curing conditions, presenting significant challenges in achieving consistent strength. To enhance the strength and mechanical properties of GPC with sodium hydroxide (NaOH), a unique approach using Gegenbauer graph neural networks (GGNN) is presented in this work. The main objectives of this study include reducing CO2 emissions. The strength of GPC with NaOH is predicted using GGNN. The GGNN method is also used to analyze the mechanical properties of GPC under different NaOH molarities and different ratios of sodium silicate to NaOH. The proposed method is simulated in MATLAB and is compared with existing methods like long short-term memory (LSTM), artificial neural network (ANN), and back propagation neural network (BPNN). It is found that the oven-cured GPC achieved better mechanical strength compared to the ambient-cured GPC. The proposed model attained the highest compressive strength (CS) of 75.42 MPa along with a high correlation coefficient of 0.9871 compared to the previous studies. In contrast to the existing methods, the proposed model achieved a high prediction accuracy of 98.5% along with a low CO2 emission of 7% demonstrating its superior performance in accurately predicting the mechanical strength and reducing carbon footprints. This indicates the robustness and reliability of the proposed model for optimizing material properties and advancing the field of sustainable construction materials.
期刊介绍:
The scope of the journal is to publish original contributions and reviews on studies, methodologies, instrumentation, and applications involving the analysis and characterization of polymers and polymeric-based materials, including synthetic polymers, blends, composites, fibers, coatings, supramolecular structures, polysaccharides, and biopolymers. The Journal will accept papers and review articles on the following topics and research areas involving fundamental and applied studies of polymer analysis and characterization:
Characterization and analysis of new and existing polymers and polymeric-based materials.
Design and evaluation of analytical instrumentation and physical testing equipment.
Determination of molecular weight, size, conformation, branching, cross-linking, chemical structure, and sequence distribution.
Using separation, spectroscopic, and scattering techniques.
Surface characterization of polymeric materials.
Measurement of solution and bulk properties and behavior of polymers.
Studies involving structure-property-processing relationships, and polymer aging.
Analysis of oligomeric materials.
Analysis of polymer additives and decomposition products.