Ruiling Hu, Lingping Jiang, Yaxin Wang, Min Zhao, Congrong Wang, Miao Zhang, Lei Yang, Wanbing Gong, Jianguo Lv
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引用次数: 0
摘要
用一种简单的方法开发高效、长期稳定的OER电催化剂对水裂解具有重要意义。然而,缺乏易于接近的活性位点和在反应过程中重构引起的耐久性下降仍然是挑战。本文采用简易电沉积方法在泡沫镍(NF)上成功制备了Ru掺杂Fe。得益于多孔结构的协同效应和活性位点的可及性,Ru-0.01-Fe/NF-2.5在电流密度为10 mA cm-2和100 mA cm-2时的OER过电位分别为134和168 mV。更重要的是,以Ru-0.01-Fe/NF-2.5和Pt/C为阳极和阴极组装的电解槽只需要1.46 V的低电压就可以实现10 mA cm-2的电流密度。此外,即使在约100 mA cm-2的高电流密度下连续运行48小时后,电解电池也保持了强大的稳定性。本研究为简便制备OER高效电催化剂开辟了道路,促进了OER高效电催化剂在工业水电解中的应用。
Constructing Ru doped Fe/nickel foam with efficient oxygen evolution reaction using a simple one-step electrodeposition technique
Developing OER electrocatalyst with high efficiency and long-term stability using a simple method is of great significance for water splitting. However, the lack of easily accessible active sites and the degradation of durability caused by reconstruction during the reaction process remain challenges. Herein, we successfully prepared Ru doped Fe on nickel foam (NF) using a facile electrodeposition method. Benefiting from the synergistic effect of porous structure and more accessible active sites, Ru-0.01-Fe/NF-2.5 posses the small OER overpotential of 134 and 168 mV at current densities of 10 and 100 mA cm-2, respectively. More significantly, the electrolytic cell assembled with Ru-0.01-Fe/NF-2.5 and Pt/C as anodes and cathodes for overall water splitting only requires a low voltage of 1.46 V to achieve the current density of 10 mA cm-2. In addition, the electrolytic cell maintained robust stability even after continuous operation of 48 hours at a high current density of approximately 100 mA cm-2. This work may open an avenue to construct OER effective electrocatalyst via facile method, and promote their applications in industrial water electrolysis.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.