İbrahim Mizan Kahyaoğlu , Ahmet Uyanık , Canan Hazal Akarsu , Tarık Küçükdeniz , Selcan Karakuş , Murat Güney
{"title":"基于地球化学分析和K-Means聚类的坝质沉积物可持续管理","authors":"İbrahim Mizan Kahyaoğlu , Ahmet Uyanık , Canan Hazal Akarsu , Tarık Küçükdeniz , Selcan Karakuş , Murat Güney","doi":"10.1016/j.aca.2025.344730","DOIUrl":null,"url":null,"abstract":"<div><div>Optimizing the use of existing dams can reduce the need for new construction and support sustainable dam management. In this study, key sediment parameters including humic acid (HA), fulvic acid (FA), %C, %H, %N, total organic matter (TOM), pH, conductivity, and shrink/swell capacity were analyzed. Heavy metal concentrations ranged from 1.62 to 7.74 mg/kg (As), 1.40–2.91 mg/kg (Cd), 6.79–18.44 mg/kg (Co), 19.46–85.61 mg/kg (Cr), 21.12–63.60 mg/kg (Cu), 8000–46,500 mg/kg (Fe), 260–1120 mg/kg (Mn), 27.12–180 mg/kg (Ni), 2.52–10.22 mg/kg (Pb), and 30.50–88.10 mg/kg (Zn). Organic material contents were 0.050–0.88 % for HA and 0.01–1.21 % for FA. Measured pH values ranged from 6.99 to 7.92, conductivity from 0.26 to 4.49 mS/cm, and shrink/swell capacity from 34.37 to 54.11 %. The dataset was normalized using Min-Max scaling to ensure consistency and reduce bias. K-means clustering was applied to identify sediment profiles, yielding insights into pollution levels, soil fertility, and retention capacity. The integration of geochemical analysis with artificial intelligence (AI)-based clustering demonstrated the effectiveness of machine learning (ML) methods in classifying sediments based on heavy metal concentrations. Additionally, SEM analysis revealed distinct layered surface properties with nanoglobular structures ranging from 100 nm to less than 10 nm, offering further insights into the sediment characteristics and potential agricultural applications. This study underscores the importance of integrating AI techniques with traditional analyses to enhance sediment characterization and promote sustainable environmental management.</div></div>","PeriodicalId":240,"journal":{"name":"Analytica Chimica Acta","volume":"1379 ","pages":"Article 344730"},"PeriodicalIF":6.0000,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Integration of geochemical analysis and K-means clustering for sustainable management of various dam sediments\",\"authors\":\"İbrahim Mizan Kahyaoğlu , Ahmet Uyanık , Canan Hazal Akarsu , Tarık Küçükdeniz , Selcan Karakuş , Murat Güney\",\"doi\":\"10.1016/j.aca.2025.344730\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Optimizing the use of existing dams can reduce the need for new construction and support sustainable dam management. In this study, key sediment parameters including humic acid (HA), fulvic acid (FA), %C, %H, %N, total organic matter (TOM), pH, conductivity, and shrink/swell capacity were analyzed. Heavy metal concentrations ranged from 1.62 to 7.74 mg/kg (As), 1.40–2.91 mg/kg (Cd), 6.79–18.44 mg/kg (Co), 19.46–85.61 mg/kg (Cr), 21.12–63.60 mg/kg (Cu), 8000–46,500 mg/kg (Fe), 260–1120 mg/kg (Mn), 27.12–180 mg/kg (Ni), 2.52–10.22 mg/kg (Pb), and 30.50–88.10 mg/kg (Zn). Organic material contents were 0.050–0.88 % for HA and 0.01–1.21 % for FA. Measured pH values ranged from 6.99 to 7.92, conductivity from 0.26 to 4.49 mS/cm, and shrink/swell capacity from 34.37 to 54.11 %. The dataset was normalized using Min-Max scaling to ensure consistency and reduce bias. K-means clustering was applied to identify sediment profiles, yielding insights into pollution levels, soil fertility, and retention capacity. The integration of geochemical analysis with artificial intelligence (AI)-based clustering demonstrated the effectiveness of machine learning (ML) methods in classifying sediments based on heavy metal concentrations. Additionally, SEM analysis revealed distinct layered surface properties with nanoglobular structures ranging from 100 nm to less than 10 nm, offering further insights into the sediment characteristics and potential agricultural applications. This study underscores the importance of integrating AI techniques with traditional analyses to enhance sediment characterization and promote sustainable environmental management.</div></div>\",\"PeriodicalId\":240,\"journal\":{\"name\":\"Analytica Chimica Acta\",\"volume\":\"1379 \",\"pages\":\"Article 344730\"},\"PeriodicalIF\":6.0000,\"publicationDate\":\"2025-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytica Chimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0003267025011249\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0003267025011249","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Integration of geochemical analysis and K-means clustering for sustainable management of various dam sediments
Optimizing the use of existing dams can reduce the need for new construction and support sustainable dam management. In this study, key sediment parameters including humic acid (HA), fulvic acid (FA), %C, %H, %N, total organic matter (TOM), pH, conductivity, and shrink/swell capacity were analyzed. Heavy metal concentrations ranged from 1.62 to 7.74 mg/kg (As), 1.40–2.91 mg/kg (Cd), 6.79–18.44 mg/kg (Co), 19.46–85.61 mg/kg (Cr), 21.12–63.60 mg/kg (Cu), 8000–46,500 mg/kg (Fe), 260–1120 mg/kg (Mn), 27.12–180 mg/kg (Ni), 2.52–10.22 mg/kg (Pb), and 30.50–88.10 mg/kg (Zn). Organic material contents were 0.050–0.88 % for HA and 0.01–1.21 % for FA. Measured pH values ranged from 6.99 to 7.92, conductivity from 0.26 to 4.49 mS/cm, and shrink/swell capacity from 34.37 to 54.11 %. The dataset was normalized using Min-Max scaling to ensure consistency and reduce bias. K-means clustering was applied to identify sediment profiles, yielding insights into pollution levels, soil fertility, and retention capacity. The integration of geochemical analysis with artificial intelligence (AI)-based clustering demonstrated the effectiveness of machine learning (ML) methods in classifying sediments based on heavy metal concentrations. Additionally, SEM analysis revealed distinct layered surface properties with nanoglobular structures ranging from 100 nm to less than 10 nm, offering further insights into the sediment characteristics and potential agricultural applications. This study underscores the importance of integrating AI techniques with traditional analyses to enhance sediment characterization and promote sustainable environmental management.
期刊介绍:
Analytica Chimica Acta has an open access mirror journal Analytica Chimica Acta: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Analytica Chimica Acta provides a forum for the rapid publication of original research, and critical, comprehensive reviews dealing with all aspects of fundamental and applied modern analytical chemistry. The journal welcomes the submission of research papers which report studies concerning the development of new and significant analytical methodologies. In determining the suitability of submitted articles for publication, particular scrutiny will be placed on the degree of novelty and impact of the research and the extent to which it adds to the existing body of knowledge in analytical chemistry.