{"title":"CeO2-SnO2微纳异质结构上的工程氧空位缺陷用于三乙胺快速检测和鱼类新鲜度监测","authors":"Shuang Li, Zhuo Liu, Lin Yang, Mengli Yan, Yan Xu","doi":"10.1016/j.snb.2025.138901","DOIUrl":null,"url":null,"abstract":"Oxygen vacancy defects on the surface of metal oxides can not only increase carrier density and facilitate electron transfer, but also increase more active sites, thereby significantly boosting the overall performance of sensors. In this study, a 3D bundle-like porous CeO<sub>2</sub>-SnO<sub>2</sub> heterostructure with abundant oxygen vacancy defects composed of radially cross-bundled mesoporous nanorods is successfully prepared. The synergistic effects of composition regulation, Ce<sup>4+</sup>/Ce<sup>3+</sup> valence engineering, and increased oxygen vacancy defects in the micro-nano structure enhance electron transfer at the interface, creating more active sites for triethylamine (TEA) capture. Consequently, the micro-nano structure shows an outstanding response value of 151.12 towards 100 ppm TEA at 157 °C, about six times higher than SnO<sub>2</sub>, with excellent selectivity, fast response/recovery times (9<!-- --> <!-- -->s/123<!-- --> <!-- -->s), superior anti-interference ability, and long-term stability. Also, the sensor can achieve a response value of 11.24 for TEA detection in gases from five-day-stored crucian carp at room temperature, showing potential for freshness monitoring. This work presents an effective strategy to develop TEA sensors for practical applications by using oxygen valence engineering and tailoring multi-scale pore structures in MOF-derived heterostructures.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"8 1","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Engineering oxygen vacancy defects on a CeO2-SnO2 micro-nano heterostructure for rapid triethylamine detection and fish freshness monitoring\",\"authors\":\"Shuang Li, Zhuo Liu, Lin Yang, Mengli Yan, Yan Xu\",\"doi\":\"10.1016/j.snb.2025.138901\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Oxygen vacancy defects on the surface of metal oxides can not only increase carrier density and facilitate electron transfer, but also increase more active sites, thereby significantly boosting the overall performance of sensors. In this study, a 3D bundle-like porous CeO<sub>2</sub>-SnO<sub>2</sub> heterostructure with abundant oxygen vacancy defects composed of radially cross-bundled mesoporous nanorods is successfully prepared. The synergistic effects of composition regulation, Ce<sup>4+</sup>/Ce<sup>3+</sup> valence engineering, and increased oxygen vacancy defects in the micro-nano structure enhance electron transfer at the interface, creating more active sites for triethylamine (TEA) capture. Consequently, the micro-nano structure shows an outstanding response value of 151.12 towards 100 ppm TEA at 157 °C, about six times higher than SnO<sub>2</sub>, with excellent selectivity, fast response/recovery times (9<!-- --> <!-- -->s/123<!-- --> <!-- -->s), superior anti-interference ability, and long-term stability. Also, the sensor can achieve a response value of 11.24 for TEA detection in gases from five-day-stored crucian carp at room temperature, showing potential for freshness monitoring. This work presents an effective strategy to develop TEA sensors for practical applications by using oxygen valence engineering and tailoring multi-scale pore structures in MOF-derived heterostructures.\",\"PeriodicalId\":425,\"journal\":{\"name\":\"Sensors and Actuators B: Chemical\",\"volume\":\"8 1\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2025-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sensors and Actuators B: Chemical\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1016/j.snb.2025.138901\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sensors and Actuators B: Chemical","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.snb.2025.138901","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Engineering oxygen vacancy defects on a CeO2-SnO2 micro-nano heterostructure for rapid triethylamine detection and fish freshness monitoring
Oxygen vacancy defects on the surface of metal oxides can not only increase carrier density and facilitate electron transfer, but also increase more active sites, thereby significantly boosting the overall performance of sensors. In this study, a 3D bundle-like porous CeO2-SnO2 heterostructure with abundant oxygen vacancy defects composed of radially cross-bundled mesoporous nanorods is successfully prepared. The synergistic effects of composition regulation, Ce4+/Ce3+ valence engineering, and increased oxygen vacancy defects in the micro-nano structure enhance electron transfer at the interface, creating more active sites for triethylamine (TEA) capture. Consequently, the micro-nano structure shows an outstanding response value of 151.12 towards 100 ppm TEA at 157 °C, about six times higher than SnO2, with excellent selectivity, fast response/recovery times (9 s/123 s), superior anti-interference ability, and long-term stability. Also, the sensor can achieve a response value of 11.24 for TEA detection in gases from five-day-stored crucian carp at room temperature, showing potential for freshness monitoring. This work presents an effective strategy to develop TEA sensors for practical applications by using oxygen valence engineering and tailoring multi-scale pore structures in MOF-derived heterostructures.
期刊介绍:
Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.