蓝发射量子点材料协同增强策略综述。

IF 3.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yue Chen, Yuting Bai, Zunxian Yang, Xudong Jiang, Benfang Liu, Jiajie Hong, Zhezhou Fang, Jinzhu Gao, Zheyu Zhou, Runsen Yu, Zhiyu Yuan, Tailiang Guo, Fushan Li, Yongyi Chen, Zhenzhen Weng
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引用次数: 0

摘要

蓝色发射量子点是下一代光电应用中非常理想的,因为它们具有特殊的颜色纯度和光谱可调的发射。然而,它们的PLQY和器件EQE明显落后于红色和绿色量子点。这种不足源于三个基本因素的协同相互作用:(i)蓝色发射所需的小颗粒尺寸固有的高密度表面缺陷和悬空键;(ii)由宽带隙产生的深价带位置,这造成了明显的界面电荷注入势垒;(iii)核-壳界面或绝缘有机配体引入的附加能垒。总的来说,这些机制显著地放大了非辐射复合和俄歇损失。本文综述了从前驱体工程、元素掺杂、核壳结构优化、合金工程、表面钝化和配体设计等多个方面提高蓝色发光量子点效率的最新进展。此外,我们强调了这些方法的协同集成-例如双前驱体动力学-应变耦合协议,应力锁定梯度合金/双壳(CdZnSeS/ZnSe/ZnS)架构,配体交换级联钝化方案,以实现为先进光电器件(如高分辨率显示器,固态照明和光伏系统)定制的高性能蓝色量子点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Review: Collaborative Enhancement Strategies with Blue-Emitting Quantum Dot Materials.

Blue-emitting QDs are highly desirable for next-generation optoelectronic applications because of their exceptional color purity and spectrally tunable emission. However, their PLQY and device EQE lag significantly behind those of red and green QDs. This shortfall originates from a synergistic interplay of three fundamental factors: (i) the high density of surface defects and dangling bonds inherent to the small particle dimensions required for blue emission; (ii) the deep valence-band position arising from the wide bandgap, which imposes a pronounced interfacial charge-injection barrier; and (iii) the additional energetic barriers introduced by core-shell interfaces or insulating organic ligands. Collectively, these mechanisms markedly amplify non-radiative recombination and Auger losses. This review summarizes recent advancements in enhancing blue-emitting QD efficiency through multifaceted strategies encompassing precursor engineering, elemental doping, core-shell structure optimization, alloying engineering, surface passivation, and ligand design. Moreover, we highlight the synergistic integration of these approaches-exemplified by dual-precursor kinetic-strain coupling protocols, stress-locked gradient-alloy/dual-shell (CdZnSeS/ZnSe/ZnS) architectures, ligand-exchange cascade passivation schemes to realize high-performance blue QDs tailored for advanced optoelectronic devices such as high-resolution displays, solid-state lighting, and photovoltaic systems.

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来源期刊
Chemistry - An Asian Journal
Chemistry - An Asian Journal 化学-化学综合
CiteScore
7.00
自引率
2.40%
发文量
535
审稿时长
1.3 months
期刊介绍: Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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