香茅热解制备磺化多孔石墨炭及其在磺化碳刷上的涂层,用于单室微生物燃料电池阳极

IF 4.1 4区 工程技术 Q3 ENERGY & FUELS
Rinki, Dipankar Saha,  Geetanjali, Deepak Kumar, Patit Paban Kundu
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引用次数: 0

摘要

对生物质废弃物产生的石墨化碳阳极用于单室微生物燃料电池(SMFC)的关注在文献中非常有限。此外,接枝以及磺化过程几乎没有被探索过。因此,本研究采用了一种合成方法,其中柠檬草衍生的石墨化碳通过磺化(S-KLg)活化。其次,以戊二醛为接枝剂(表示为S-KLg@GCB),采用接枝工艺将其接枝到磺酸功能化碳纤维刷上,用于SMFC。结果表明,S-KLg具有三维多孔结构,表明微生物可能粘附和生长,并且具有高电导率和高电容。此外,以S-KLg@GCB为阳极的SMFC的功率密度显著增加,其相应值为1452.7 mW/m3,是普通碳刷阳极的1.95倍。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development of sulfonated porous graphitized carbon by pyrolysis from lemongrass and its coating on sulfonated carbon brush for use as anode in single chambered microbial fuel cell

The focus on the biomass waste-generated graphitized carbon-employed anode for the single-chambered microbial fuel cell (SMFC) is extremely limited in the literature. Additionally, grafting, as well as the sulfonation process, has been hardly explored. Thus, this present investigation incorporates a synthetic approach in which lemongrass-derived graphitized carbon is activated through sulfonation (S-KLg). Furthermore, it is attached to sulfonic acid functionalized carbon fibers brush by employing the grafting process using glutaraldehyde as a grafting agent (denoted as S-KLg@GCB), for the application in SMFC. The results suggest that S-KLg possesses a three-dimensional porous structure, signifying the likelihood of adhesion and growth of microorganisms, and it also exhibited high conductivity and capacitance. Furthermore, the SMFC with S-KLg@GCB as an anode has shown a significant augmentation in the power density with a corresponding value of 1452.7 mW/m3, which is 1.95 times higher than that of a plain carbon brush anode.

Graphical abstract

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来源期刊
Biomass Conversion and Biorefinery
Biomass Conversion and Biorefinery Energy-Renewable Energy, Sustainability and the Environment
CiteScore
7.00
自引率
15.00%
发文量
1358
期刊介绍: Biomass Conversion and Biorefinery presents articles and information on research, development and applications in thermo-chemical conversion; physico-chemical conversion and bio-chemical conversion, including all necessary steps for the provision and preparation of the biomass as well as all possible downstream processing steps for the environmentally sound and economically viable provision of energy and chemical products.
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