{"title":"稻壳和纺织废料化学循环共气化作为水泥替代燃料的过程模拟和BPNNM预测","authors":"Congxi Tao, Hao Wang, Qingmei Li, Minghai He, Qian Liang, Xudong Wang","doi":"10.1007/s13399-025-06871-4","DOIUrl":null,"url":null,"abstract":"<div><p>Chemical looping gasification (CLG) can inherently split the traditional gasification into two processes to produce high-quality syngas, avoiding the N<sub>2</sub> dilution for syngas. CLG of solid wastes has gained attention for its satisfactory performance with waste valorization. The chemical looping co-gasification (CLCG) performances of rice husk and textile wastes are investigated, which are typical solid wastes used in industry as alternative fuels. A thermodynamic process model of CLCG is established, and the effects of different operating parameters are quantitatively analyzed. Furthermore, a multi-input and multi-output back propagation neural network model (BPNNM) is trained using process model results for the performance prediction. Key findings reveal that increasing equivalence ratios of oxygen carrier and steam (<i>α</i><sub>OC/F</sub> and <i>α</i><sub>steam/F</sub>) significantly affect gasification efficiency. Specifically, increasing <i>α</i><sub>OC/F</sub> to 0.5 decreases gasification efficiency to 60.82%. Conversely, increasing <i>α</i><sub>steam/F</sub> from 0.1 to 0.5 leads to a slight decrease in gasification efficiency from 85.95 to 84.80%, while simultaneously increasing hydrogen concentration in syngas from 39.91 to 46.28%. Elevating the gasification temperature from 650 to 850 °C can raise the <i>η</i> from 81.52% up to 86.00%. The blending ratio of the rice husk and textile waste also dramatically affects gasification efficiency, with efficiency decreasing from 92.27 to 74.41% as the blending ratio <i>R</i><sub>r</sub> increases from 0 to 1. The tests of random conditions demonstrate that the trained BPNNM can be a very accurate tool for the prediction of syngas compositions and gasification indicators in CLCG.</p></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 18","pages":"25289 - 25305"},"PeriodicalIF":4.1000,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Process simulation and BPNNM prediction for chemical looping co-gasification of rice husk and textile wastes as cement alternative fuels\",\"authors\":\"Congxi Tao, Hao Wang, Qingmei Li, Minghai He, Qian Liang, Xudong Wang\",\"doi\":\"10.1007/s13399-025-06871-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Chemical looping gasification (CLG) can inherently split the traditional gasification into two processes to produce high-quality syngas, avoiding the N<sub>2</sub> dilution for syngas. CLG of solid wastes has gained attention for its satisfactory performance with waste valorization. The chemical looping co-gasification (CLCG) performances of rice husk and textile wastes are investigated, which are typical solid wastes used in industry as alternative fuels. A thermodynamic process model of CLCG is established, and the effects of different operating parameters are quantitatively analyzed. Furthermore, a multi-input and multi-output back propagation neural network model (BPNNM) is trained using process model results for the performance prediction. Key findings reveal that increasing equivalence ratios of oxygen carrier and steam (<i>α</i><sub>OC/F</sub> and <i>α</i><sub>steam/F</sub>) significantly affect gasification efficiency. Specifically, increasing <i>α</i><sub>OC/F</sub> to 0.5 decreases gasification efficiency to 60.82%. Conversely, increasing <i>α</i><sub>steam/F</sub> from 0.1 to 0.5 leads to a slight decrease in gasification efficiency from 85.95 to 84.80%, while simultaneously increasing hydrogen concentration in syngas from 39.91 to 46.28%. Elevating the gasification temperature from 650 to 850 °C can raise the <i>η</i> from 81.52% up to 86.00%. The blending ratio of the rice husk and textile waste also dramatically affects gasification efficiency, with efficiency decreasing from 92.27 to 74.41% as the blending ratio <i>R</i><sub>r</sub> increases from 0 to 1. The tests of random conditions demonstrate that the trained BPNNM can be a very accurate tool for the prediction of syngas compositions and gasification indicators in CLCG.</p></div>\",\"PeriodicalId\":488,\"journal\":{\"name\":\"Biomass Conversion and Biorefinery\",\"volume\":\"15 18\",\"pages\":\"25289 - 25305\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2025-04-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Biomass Conversion and Biorefinery\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13399-025-06871-4\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Biomass Conversion and Biorefinery","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s13399-025-06871-4","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Process simulation and BPNNM prediction for chemical looping co-gasification of rice husk and textile wastes as cement alternative fuels
Chemical looping gasification (CLG) can inherently split the traditional gasification into two processes to produce high-quality syngas, avoiding the N2 dilution for syngas. CLG of solid wastes has gained attention for its satisfactory performance with waste valorization. The chemical looping co-gasification (CLCG) performances of rice husk and textile wastes are investigated, which are typical solid wastes used in industry as alternative fuels. A thermodynamic process model of CLCG is established, and the effects of different operating parameters are quantitatively analyzed. Furthermore, a multi-input and multi-output back propagation neural network model (BPNNM) is trained using process model results for the performance prediction. Key findings reveal that increasing equivalence ratios of oxygen carrier and steam (αOC/F and αsteam/F) significantly affect gasification efficiency. Specifically, increasing αOC/F to 0.5 decreases gasification efficiency to 60.82%. Conversely, increasing αsteam/F from 0.1 to 0.5 leads to a slight decrease in gasification efficiency from 85.95 to 84.80%, while simultaneously increasing hydrogen concentration in syngas from 39.91 to 46.28%. Elevating the gasification temperature from 650 to 850 °C can raise the η from 81.52% up to 86.00%. The blending ratio of the rice husk and textile waste also dramatically affects gasification efficiency, with efficiency decreasing from 92.27 to 74.41% as the blending ratio Rr increases from 0 to 1. The tests of random conditions demonstrate that the trained BPNNM can be a very accurate tool for the prediction of syngas compositions and gasification indicators in CLCG.
期刊介绍:
Biomass Conversion and Biorefinery presents articles and information on research, development and applications in thermo-chemical conversion; physico-chemical conversion and bio-chemical conversion, including all necessary steps for the provision and preparation of the biomass as well as all possible downstream processing steps for the environmentally sound and economically viable provision of energy and chemical products.