{"title":"钙钛矿上单原子锚定与强金属-氧化物相互作用的高效高温CO2电解。","authors":"Feng Hu,Beibei He,Kongfa Chen,Wenjia Ma,Yonglong Huang,Sunce Zhao,Yu Chen,Ling Zhao","doi":"10.1002/adma.202512310","DOIUrl":null,"url":null,"abstract":"Efficient electrochemical CO2 reduction remains a grand challenge in advancing carbon-neutral energy technologies. Here, an efficient solid-state approach for the fabrication of a novel single-atom Ir anchored Sr2Fe1.5Mo0.5O6-δ (SFM) perovskite electrocatalyst, designed for high temperature CO2 electrolysis in solid oxide electrolysis cells (SOECs) is reported. The resulting four-coordinated Ir-O-Fe/Mo configuration induces pronounced interfacial electronic reconstruction and strong metal-oxide interaction, substantially lowering the energy barrier for CO2 electrolysis, as indicated by extended X-ray absorption fine structure (EXAFS) analysis and density functional theory (DFT) calculations. When employed as a cathode in SOECs, the 2Ir/SFM (2 wt.% Ir) electrocatalyst achieves a high current density of 1.63 A cm-2 at 1.5 V and 800 °C, along with excellent Faradaic efficiency and long-term operational stability. These findings offer atomistic insights into the structure-performance relationship of single-atom/perovskite heterostructures, underscoring the commercial potential of SOECs for CO2 electrolysis.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"17 1","pages":"e12310"},"PeriodicalIF":26.8000,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Single-Atom Anchored on Perovskite With Strong Metal-Oxide Interaction for Efficient High Temperature CO2 Electrolysis.\",\"authors\":\"Feng Hu,Beibei He,Kongfa Chen,Wenjia Ma,Yonglong Huang,Sunce Zhao,Yu Chen,Ling Zhao\",\"doi\":\"10.1002/adma.202512310\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Efficient electrochemical CO2 reduction remains a grand challenge in advancing carbon-neutral energy technologies. Here, an efficient solid-state approach for the fabrication of a novel single-atom Ir anchored Sr2Fe1.5Mo0.5O6-δ (SFM) perovskite electrocatalyst, designed for high temperature CO2 electrolysis in solid oxide electrolysis cells (SOECs) is reported. The resulting four-coordinated Ir-O-Fe/Mo configuration induces pronounced interfacial electronic reconstruction and strong metal-oxide interaction, substantially lowering the energy barrier for CO2 electrolysis, as indicated by extended X-ray absorption fine structure (EXAFS) analysis and density functional theory (DFT) calculations. When employed as a cathode in SOECs, the 2Ir/SFM (2 wt.% Ir) electrocatalyst achieves a high current density of 1.63 A cm-2 at 1.5 V and 800 °C, along with excellent Faradaic efficiency and long-term operational stability. These findings offer atomistic insights into the structure-performance relationship of single-atom/perovskite heterostructures, underscoring the commercial potential of SOECs for CO2 electrolysis.\",\"PeriodicalId\":114,\"journal\":{\"name\":\"Advanced Materials\",\"volume\":\"17 1\",\"pages\":\"e12310\"},\"PeriodicalIF\":26.8000,\"publicationDate\":\"2025-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/adma.202512310\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202512310","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
在推进碳中和能源技术中,高效的电化学二氧化碳还原仍然是一个巨大的挑战。本文报道了一种用于固体氧化物电解电池(soec)高温CO2电解的新型单原子Ir锚定Sr2Fe1.5Mo0.5O6-δ (SFM)钙钛矿电催化剂的高效固态制备方法。扩展x射线吸收精细结构(EXAFS)分析和密度泛函理论(DFT)计算表明,由此产生的四配位Ir-O-Fe/Mo构型诱导了明显的界面电子重构和强金属-氧化物相互作用,大大降低了CO2电解的能垒。当用作soec的阴极时,2Ir/SFM (2 wt.% Ir)电催化剂在1.5 V和800°C下实现了1.63 a cm-2的高电流密度,同时具有优异的法拉第效率和长期工作稳定性。这些发现为单原子/钙钛矿异质结构的结构-性能关系提供了原子层面的见解,强调了soec用于CO2电解的商业潜力。
Single-Atom Anchored on Perovskite With Strong Metal-Oxide Interaction for Efficient High Temperature CO2 Electrolysis.
Efficient electrochemical CO2 reduction remains a grand challenge in advancing carbon-neutral energy technologies. Here, an efficient solid-state approach for the fabrication of a novel single-atom Ir anchored Sr2Fe1.5Mo0.5O6-δ (SFM) perovskite electrocatalyst, designed for high temperature CO2 electrolysis in solid oxide electrolysis cells (SOECs) is reported. The resulting four-coordinated Ir-O-Fe/Mo configuration induces pronounced interfacial electronic reconstruction and strong metal-oxide interaction, substantially lowering the energy barrier for CO2 electrolysis, as indicated by extended X-ray absorption fine structure (EXAFS) analysis and density functional theory (DFT) calculations. When employed as a cathode in SOECs, the 2Ir/SFM (2 wt.% Ir) electrocatalyst achieves a high current density of 1.63 A cm-2 at 1.5 V and 800 °C, along with excellent Faradaic efficiency and long-term operational stability. These findings offer atomistic insights into the structure-performance relationship of single-atom/perovskite heterostructures, underscoring the commercial potential of SOECs for CO2 electrolysis.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.