钴催化的碘化烷基氨基羰基化反应

IF 6.5 1区化学 Q2 CHEMISTRY, PHYSICAL

Journal of Catalysis Pub Date : 2025-09-27 DOI:10.1016/j.jcat.2025.116456

Guang Xu , Zhi-Peng Bao , Xiao-Feng Wu

引用次数: 0

摘要

酰胺是一种有价值的化合物，在各个领域都有重要的应用。本文报道了一种新的钴催化碘化烷基与胺羰基化反应，该反应具有反应条件温和、可扩展性好等优点。机制研究表明，该反应是通过自由基SET途径进行的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cobalt-catalyzed aminocarbonylation of alkyl iodides

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Cobalt-catalyzed aminocarbonylation of alkyl iodides

Amides are valuable compounds with important applications in various areas. Herein, a new cobalt-catalyzed carbonylation of alkyl iodides with amines was reported, which has the advantages of mild reaction conditions and scalability. Mechanistic studies indicate that this reaction proceeds via a radical SET pathway.

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来源期刊

Journal of Catalysis 工程技术-工程：化工

CiteScore

12.30

自引率

5.50%

发文量

447

审稿时长

31 days

期刊介绍： The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes. The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods. The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.