{"title":"纳米sic负载对聚酰亚胺高频电应力下表面放电性能的影响。","authors":"Ruoqing Hong, Qingmin Li, Huan Li, Qingming Xin","doi":"10.3390/polym17182526","DOIUrl":null,"url":null,"abstract":"<p><p>This study targets insulation challenges in high-frequency power transformers (HFPTs), which are an integral part of the high-voltage, high-capacity isolated DC/DC converter under development for offshore renewable energy systems. We propose a nano-silicon carbide (SiC)-doped polyimide (PI) winding insulation strategy to enhance discharge resistance and thermal stability under high-frequency electric stress. Experimental results show that 10 wt% SiC doping significantly improves insulation performance, extending failure time from 17 to 50 min and reducing maximum discharge amplitude by 76%, owing to enhanced charge trapping and interfacial polarization suppression. Surface and volume resistivity measurements further confirmed the improvement; at 120 °C, the 10 wt% SiC composite maintained high surface resistivity 3.30 × 10<sup>14</sup> Ω and volume resistivity 1.41 × 10<sup>15</sup> Ω·cm, significantly outperforming pure PI. In contrast, 20 wt% SiC, though still resistive, showed reduced stability due to agglomeration and interfacial defects, with a surface resistivity of 2.07 × 10<sup>14</sup> Ω and degraded dielectric performance. Dielectric analysis revealed that 10 wt% SiC suppressed dielectric constant and loss across the frequency range, while 20 wt% SiC exhibited increased values at high frequency. These results highlight 10 wt% SiC as an optimal formulation for HFPT winding insulation.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"17 18","pages":""},"PeriodicalIF":4.9000,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12473874/pdf/","citationCount":"0","resultStr":"{\"title\":\"Effect of Nano-SiC Loading on Surface Discharge Performance of Polyimide at High-Frequency Electric Stress.\",\"authors\":\"Ruoqing Hong, Qingmin Li, Huan Li, Qingming Xin\",\"doi\":\"10.3390/polym17182526\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>This study targets insulation challenges in high-frequency power transformers (HFPTs), which are an integral part of the high-voltage, high-capacity isolated DC/DC converter under development for offshore renewable energy systems. We propose a nano-silicon carbide (SiC)-doped polyimide (PI) winding insulation strategy to enhance discharge resistance and thermal stability under high-frequency electric stress. Experimental results show that 10 wt% SiC doping significantly improves insulation performance, extending failure time from 17 to 50 min and reducing maximum discharge amplitude by 76%, owing to enhanced charge trapping and interfacial polarization suppression. Surface and volume resistivity measurements further confirmed the improvement; at 120 °C, the 10 wt% SiC composite maintained high surface resistivity 3.30 × 10<sup>14</sup> Ω and volume resistivity 1.41 × 10<sup>15</sup> Ω·cm, significantly outperforming pure PI. In contrast, 20 wt% SiC, though still resistive, showed reduced stability due to agglomeration and interfacial defects, with a surface resistivity of 2.07 × 10<sup>14</sup> Ω and degraded dielectric performance. Dielectric analysis revealed that 10 wt% SiC suppressed dielectric constant and loss across the frequency range, while 20 wt% SiC exhibited increased values at high frequency. These results highlight 10 wt% SiC as an optimal formulation for HFPT winding insulation.</p>\",\"PeriodicalId\":20416,\"journal\":{\"name\":\"Polymers\",\"volume\":\"17 18\",\"pages\":\"\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2025-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12473874/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.3390/polym17182526\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymers","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.3390/polym17182526","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Effect of Nano-SiC Loading on Surface Discharge Performance of Polyimide at High-Frequency Electric Stress.
This study targets insulation challenges in high-frequency power transformers (HFPTs), which are an integral part of the high-voltage, high-capacity isolated DC/DC converter under development for offshore renewable energy systems. We propose a nano-silicon carbide (SiC)-doped polyimide (PI) winding insulation strategy to enhance discharge resistance and thermal stability under high-frequency electric stress. Experimental results show that 10 wt% SiC doping significantly improves insulation performance, extending failure time from 17 to 50 min and reducing maximum discharge amplitude by 76%, owing to enhanced charge trapping and interfacial polarization suppression. Surface and volume resistivity measurements further confirmed the improvement; at 120 °C, the 10 wt% SiC composite maintained high surface resistivity 3.30 × 1014 Ω and volume resistivity 1.41 × 1015 Ω·cm, significantly outperforming pure PI. In contrast, 20 wt% SiC, though still resistive, showed reduced stability due to agglomeration and interfacial defects, with a surface resistivity of 2.07 × 1014 Ω and degraded dielectric performance. Dielectric analysis revealed that 10 wt% SiC suppressed dielectric constant and loss across the frequency range, while 20 wt% SiC exhibited increased values at high frequency. These results highlight 10 wt% SiC as an optimal formulation for HFPT winding insulation.
期刊介绍:
Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.