Bio-Based Aqueous Dispersions Based on Unsaturated PLA Polymers for Barrier Packaging Applications.

The growing demand for sustainable packaging materials highlights the need for bio-based alternatives to fossil-derived polymers, particularly in barrier applications where reduced environmental impact and recyclability are critical. Poly(lactic acid) is a promising candidate due to its renewable origin and biodegradability, yet its application in aqueous dispersion coatings remains underdeveloped. In this study, copolymers were synthesized from L-(+)-lactic acid, itaconic acid, and 1,4-/2,3-butanediol via polycondensation, and a solvent-free thermomechanical method was used to prepare aqueous dispersions from the produced copolymers. The main objective of this study was to identify an optimal composition for the copolymer and dispersion to achieve small and uniformly sized dispersion particles while also assessing the scalability of the process from laboratory to pilot production. The smallest dispersion particles and most uniform size distribution were achieved with a copolymer that had an M_n close to the average (10,180 g mol^-1) and a low T_g (-1.4 °C). The grade and dosage of the dispersion stabilizer significantly influenced the particle size and particle size distribution. The process scale-up, including polymer production at pilot scale and dispersion preparation at bench scale, was successfully demonstrated. The water vapor barrier properties of the coated dispersions were promising (<10 g/m² at 23 °C/50% RH), supporting the potential of aqueous PLA-based dispersions as sustainable barrier coatings.