纳米二氧化硅填料填充NR/NBR橡胶复合材料的形貌与性能

IF 1.5 4区 化学 Q4 POLYMER SCIENCE
V. Sivaramakrishnan, S. Vishvanathperumal, V. Navaneethakrishnan, G. Anand
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引用次数: 0

摘要

以环氧化天然橡胶(ENR)为增容剂,研究了改性纳米二氧化硅(mNS)对天然橡胶(NR)和丙烯腈丁二烯橡胶(NBR)复合材料的补强效果。研究了纳米二氧化硅(NS)填充纳米复合材料,并对其形态、流变学和力学性能进行了系统分析。主要研究结果表明,将mNS含量从0增加到10 phr可以提高材料的力学性能,包括硬度、抗撕裂性和耐磨性。值得注意的是,与未填充的NR/NBR相比,添加6phr mNS的70/30 NR/NBR共混物在100%伸长率下的拉伸强度增加了128%,应力增加了58%。这些改进是由于mNS的高表面积和均匀分散,增强了聚合物基体内的界面相互作用。此外,更高的mNS浓度提高了抗膨胀性,增强了纳米填料在提高复合材料整体性能方面的有效性。这些发现突出了mns增强NR/NBR复合材料在高级弹性体应用中的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Morphology and performance of nanosilica filler filled NR/NBR rubber composites

This study investigates the reinforcing effect of modified nanosilica (mNS) on natural rubber (NR) and acrylonitrile butadiene rubber (NBR) composites, with epoxidized natural rubber (ENR) used as a compatibilizer. Nanosilica (NS)-filled nanocomposites were developed and systematically analyzed for their morphological, rheological, and mechanical properties. Key findings indicate that increasing the mNS content from 0 to 10 phr enhances mechanical performance, including hardness, tear resistance, and abrasion resistance. Notably, the 70/30 NR/NBR blend with 6 phr of mNS exhibited a 128% increase in tensile strength and a 58% rise in stress at 100% elongation compared to unfilled NR/NBR. These improvements are attributed to the high surface area and uniform dispersion of mNS, which enhance interfacial interactions within the polymer matrix. Furthermore, higher mNS concentrations improved swelling resistance, reinforcing the nanofiller’s effectiveness in enhancing overall composite performance. These findings highlight the potential of mNS-reinforced NR/NBR composites for advanced elastomer applications.

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来源期刊
Journal of Rubber Research
Journal of Rubber Research 化学-高分子科学
自引率
15.40%
发文量
46
审稿时长
3 months
期刊介绍: The Journal of Rubber Research is devoted to both natural and synthetic rubbers, as well as to related disciplines. The scope of the journal encompasses all aspects of rubber from the core disciplines of biology, physics and chemistry, as well as economics. As a specialised field, rubber science includes within its niche a vast potential of innovative and value-added research areas yet to be explored. This peer reviewed publication focuses on the results of active experimental research and authoritative reviews on all aspects of rubber science. The Journal of Rubber Research welcomes research on: the upstream, including crop management, crop improvement and protection, and biotechnology; the midstream, including processing and effluent management; the downstream, including rubber engineering and product design, advanced rubber technology, latex science and technology, and chemistry and materials exploratory; economics, including the economics of rubber production, consumption, and market analysis. The Journal of Rubber Research serves to build a collective knowledge base while communicating information and validating the quality of research within the discipline, and bringing together work from experts in rubber science and related disciplines. Scientists in both academia and industry involved in researching and working with all aspects of rubber will find this journal to be both source of information and a gateway for their own publications.
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